REACTIONS OF OTHER NITROGEN COMPOUNDS

Reactions of nitrogen compounds, other than those involving active nitrogen, which also do not involve oxidation are few in number. The material presented below deals with some of these reactions which have not been discussed earlier in this review. [Pg.256]

The reaction between hydrogen atoms and hydrazine in a flow system has been investigated by Schiavello and Volpi . Hydrogen atoms produced in a micro-wave discharge were flowed into a vessel along with N2H4, under stirred reactor conditions. Under steady-state conditions the reactor vessel was sampled through a pin hole leak (25 /rm diameter) which led directly to a mass spectrometer ion source. [Pg.256]

The main features of the reaction are adequately explained by the by the mechanism [Pg.256]

H-f-N2H4 H2 + N2H3 2N2H3 2NH3 + N2 H + N2H3 H2+N2H2 N2H2 H2 + N2 [Pg.256]

Reactions (3) and (4) are of minor importance. The rate coefficient for reaction (1) was found to be [Pg.256]

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