Reactions of Enines Derived from Allylic Substitution Products

Reactions of Enines Derived from Allylic Substitution Products 

The asymmetric Ir-catalyzed allylic substitution reaction has recently been developed into a broadly applicable synthetic method. In particular, isolated (ir-allyl)Ir complexes derived from phosphoramidites are effective single-species catalysts. As ancillary ligand, the standard cod has been supplemented with 

The work described here was supported by the Deutsche Forschungsgemeinschaft (SFB 623), the Graduiertenkolleg 850, and, concerning applications in natural products synthesis, by the Dr. Rainer Wild-Stiftung. Donation of enantiopure 1-arylethylamines by Prof. Dr. K. Ditrich, BASF SE, is gratefully acknowledged. 

Grubbs, R.H. (ed.) (2003) Handbook of Metathesis, John Wiley Sons, Inc., 

Review Leahy, D.K. and Evans, P.A. (2005) in Modern Rhodium-Catalyzed Organic Reactions (ed. P.A. Evans), John Wiley Sons, Inc., New York, p. 191. 

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