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Reaction with PCI

For reactions with ammonia analogous products such as HN=PCl3 and HN =P(NH,)3 were proposed, but characterization was hampered by incomplete reactions, separation-resistant mixtures, and sensitivity to moisture. Furthermore, gradual polymerization occurred with loss of ammonia to yield phosph.im , a poorly characterized solid of approximate formula (PN2H)r us the ullimuie product. If instead of free ammonia its less reactive conjugate acid is used, reaction with PCI, proceeds at a moderate rate and the results are more definitive ... [Pg.920]

See other pages where Reaction with PCI is mentioned: [Pg.284]    [Pg.442]    [Pg.70]    [Pg.920]    [Pg.142]    [Pg.15]    [Pg.112]    [Pg.128]    [Pg.215]    [Pg.245]    [Pg.251]    [Pg.286]    [Pg.307]    [Pg.373]    [Pg.405]    [Pg.499]    [Pg.667]    [Pg.839]    [Pg.889]    [Pg.947]    [Pg.949]    [Pg.1196]   
See also in sourсe #XX -- [ Pg.5 , Pg.1195 , Pg.1349 , Pg.1415 ]



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