Reaction conditions and results

Table 4.13 Comparison of reaction conditions and results obtained in a micro reactor set-up with results obtained in a continuous stirred tank reactor [51].

Table 5.2 Comparison of reaction conditions and results for hydrogenation of methyl (Z)-a-acetamidocinnamate in mini batch, micro liquid/liquid and micro gas/liquid reactors [70. ...

Table III. Reaction Conditions and Results of Synthesis of PRO Containing Biphenyl Groups ...

Table k. Reaction conditions and results of hydroliquefaction on coals used in the study of the wide range... 

Table II. Reaction Conditions and Results for Hydrogenation of Mequinenza Lignite with Sulfided Ammonium Molybdate Catalyst...

Ring-size dependency of reaction conditions and results... 

Table 3 Reaction conditions and results for the condensation of unprotected carbohydrates with...

Table I. Reaction Conditions and Results of Cationic Copolymerizations of CEVE with Photosensitizer Monomersa...

The reactions of PCVE with PNP are quantitative under these reaction conditions, and polymeric photosensitizers such as poly[2-chloro-ethyl vinyl ether-co-2-(4-nitrophenoxy)ethyl vinyl ether] (PCVE-NPVE) containing about 4, 10, 19, 28, 37, and 46 mol-% of pendant 4-nitrophenoxy (NP) groups were prepared (Table II). Although the reactions of PCVE with PNN were carried Table II. Reaction Condition and Results of the Syntheses... 

Substitution reactions of the remaining pendant chloroethyl groups in PCVE-NPVE with 20 mol-% excess of potassium cinnamate were carried out using TBAB as a phase transfer catalyst in DMF at 100"C for 24 h. The reaction conditions and results are summarized in Table III. It should be noted that 100 mole % substitution occurred in all cases. 

As most chemical and virtually all biochemical processes occur in liquid state, solvation of the reaction partners is one of the most prominent topics for the determination of chemical reactivity and reaction mechanisms and for the control of reaction conditions and resulting materials. Besides an exhaustive investigation by various experimental methods [1,2,3], theoretical approaches have gained an increasing importance in the treatment of solvation effects [4,5,6,7,8], The reason for this is not only the need for sufficiently accurate models for a physically correct interpretation of the experimental data (Theory determines, what we observe ), but also the limitation of experimental methods in dealing with ultrafast reaction dynamics in the pico- or even subpicosecond regime. These processes have become more and more the domain of computational simulations and a critical evaluation of the accuracy of simulation methods covering experimentally inaccessible systems is of utmost importance, therefore. 

Figure 13 Reaction conditions and results obtained with phase-transfer diazocoupling reaction under microscale and macroscale condition.

Table 4 shows typical reaction conditions and results of the living cationic polymerization of isobutyl vinyl ether (IBVE) with the HCl/ZnCh [127] and the CFjCC H/ZnCL [227] initiating systems. The former system is now among the most convenient for the synthesis of poly(alkyl vinyl... 

The reaction of diethylzinc with benzaldehyde was carried out in the presence of several (R,5)-l,2-disubstituted ferrocenyl amino alcohols 20 in order to examine the effect of the structure of 20 on the enantioselectivity. The reaction conditions and results are summarized in Table 3-5. 

The reaction of diethyl- and di-n-butylzinc with o-phthalaldehyde 37 was carried out in the presence of 20o, (S,I )-20o, or 28 — 29 (5 — 10 mol%) in hexane at room temperature to afford monoadducts 38 with high optical purity. Powdered o-phthalaldehyde is only slightly soluble in hexane, but gradually went into solution during the reaction, and an almost clear solution was obtained at the end point. The diastereomer ratio of lactols 38 at the 1-position was determined to be 1 1 by NMR spectroscopy. The reaction conditions and results are summarized in Table 3-10. 

Table 3. Reaction conditions and results of RCH/RP process (15-year, average) Parameter Typical values...

Table 2. Hydroxylation of phenolon TS-1. Summary of reaction conditions and results. ...

Typical reaction conditions and results are as follows temperature, 120-150° C. pressure, 14-17 atmospheres feed rate, 0.5-1.0 volumes liquid butane per volume of bauxite per hour conversion to isobutane, 40-50% catalyst life, 180 gallons isobutane per pound of aluminum chloride, or 60 gallons isobutane per pound of bauxite. 

Table 9.1 Reaction conditions and results for the AIBN-initiated telomerization ofVFj in supercritical CO2 at T=60°C in a 10-mL stainless steel view cell for 24 h.

Table 9.2 Reaction conditions and results for the thermally-initiated telo-merization ofTFE at 7=180°C in a 25-mL view cell (pressures varied based on telomer concentration, between 17 and 22 MPa).

DeSimone and coworkers recently reported the photooxidation of various concentrations of HFP in CO2 in concert with parallel reactions carried out in bulk HFP and in perfluorocyclobutane for purposes of comparison [42]. Scheme 9.5 and Table 9.4 detail the reaction conditions and results. Based on the data collected in this study, it was demonstrated that there is a strong dependence of molecular weight and composition on HFP concentration (i.e. lower HFP concentrations gave lower peroxide content). Additionally, viscosity effects in liquid CO2 appeared to significantly reduce the amount of peroxidic linkages in the final product, as seen from entries 4 and 5 in Table 9.4. 

Table 12.4 Summary of reaction conditions and results for polymerization of alkyl- and A-alkyl-substituted anilines. Adapted from ref. 26.

The kinetic parameters for the reaction between Cp"Mn(CO)2(NCMe) and FPl were elucidated by comparison of experimental and simulated voltammograms over a wide tnnperature range and reaction conditions and resulted in k(25 - L3 x 10 M s , AH - 4.4 kcal/mol, and AS ... 

---