Reaclors CSTRs

In an ideal continuously stirred tank reaclor (CSTR), the conditions are uniform throughout and the condition of the effluent is the same as the condition in the tank. When a batteiy of such vessels is employed in series, the concentration profile is step-shaped if the abscissa is the total residence time or the stage number. The residence time of individual molecules varies exponentially from zero to infinity, as illustrated in Fig. 7-2>e. 

Selectivity A significant respect in which CSTRs may differ from batch (or PFR) reaclors is in the product distribution of complex reactions. However, each particular set of reactions must be treated individually to find the superiority. For the consecutive reactions A B C, Fig. 7-5b shows that a higher peak value of B is reached in batch reactors than in CSTRs as the number of stages increases the batch performance is approached. 

Dispersion In tubes, and particiilarly in packed beds, the flow pattern is disturbed by eddies diose effect is taken into account by a dispersion coefficient in Fick s diffusion law. A PFR has a dispersion coefficient of 0 and a CSTR of oo. Some rough correlations of the Peclet number uL/D in terms of Reynolds and Schmidt numbers are Eqs. (23-47) to (23-49). There is also a relation between the Peclet number and the value of n of the RTD equation, Eq. (7-111). The dispersion model is sometimes said to be an adequate representation of a reaclor with a small deviation from phig ffow, without specifying the magnitude ol small. As a point of superiority to the RTD model, the dispersion model does have the empirical correlations that have been cited and can therefore be used for design purposes within the limits of those correlations. 

Figure 13-19 Real reaclor modeled as a CSTR and PFR in series.

Figure 14-18 Combinaiions of ideal reactors used to model real tubular reaclors, (a) two ideal PFRs in parallel (bi ideal PFR and ideal CSTR in parallel,...

Example DVD 10-6 Catalyst Decay in a Fluidized Bed Modeled as a CSTR J. Example DVDtO-S Decay in a Straight-Tlmnigh Transport Reaclor... 

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