Rate of cooling

If indirect heat transfer is used with a large temperature difference to promote high rates of cooling, then the cooling fluid (e.g., boiling water) is fixed by process requirements. In this case, the heat of reaction is not available at the temperature of the reactor effluent. Rather, the heat of reaction becomes available at the temperature of the quench fluid. Thus the feed stream to the reactor is a cold stream, the quench fluid is a hot stream, and the reactor effluent after the quench is also a hot stream. 

Properties. The crystallinity of FEP polymer is significantly lower than that of PTFE (70 vs 98%). The stmcture resembles that of PTFE, except for a random replacement of a fluorine atom by a perfluoromethyl group (CF ). The crystallinity after processing depends on the rate of cooling the molten polymer. The presence of HFP ia the polymer chain teads to distort the highly crystallized stmcture of the PTFE chaia and results ia a higher amorphous fractioa. 

Control of supersaturation is an important factor in obtaining crystal size distributions of desired characteristics, and it would be useful to have a model relating rate of cooling or evaporation or addition of diluent required to maintain a specified supersaturation in the crystallizer. Contrast this to the uncontrolled situation of natural cooling in which the heat transfer rate is given by... 

Let us consider a cooler in the equipment flow sheet. The required rate of heat removal is known from the balances, and the rate of cooling water can be calculated once the inlet and outlet temperatures of the water have been specified. The calculation of the consumption of other utilities is also straightforward. Allowances should be made for wastage. 

The diagram of the evaporator performance is shown in the Fig. 11-97. The character of the curvature of the hues (variable heat-transfer rate) indicates that the evaporator is coohng air. Influences of the flow rate of cooled fluid are also shown in this diagram i.e., higher flow rate will increase heat transfer. The same effect could be shown... 

In the most frequently used steels, having less dran the eutectoid content of carbon (about 0.8 wt%), die vaiious forms in which the cementite phase can be produced in dispersion in fenite depend upon die rate of cooling to... 

If an ascending air parcel reaches saturation, the addition of latent heat from condensing moisture will partially overcome the cooling due to expansion. Therefore, the saturated adiabatic lapse rate (of cooling) is smaller than y. ... 

It is the cooling operation that sets the shape of thermoplastics. The rate of cooling affects the process in two ways ... 

The time available for disorientation as the melt cools from Tp to T. This will depend on the value of Tp-T where is the temperature of the environment (the mould temperature in injection moulding) since this will with the specific heat determine the rate of cooling. The time will also depend on Tp-T since this will determine the extent of cooling. 

Shrinkage of about 5-10% occurs at right angles to the direction of the preforming force. The amount of shrinkage is mainly dependent on the rate of cooling, but also to a minor extent, on the preforming pressure. 

A runaway reaction occurs when an exothermic system becomes uncontrollable. The reaction leads to a rapid increase in the temperature and pressure, which if not relieved can rupture the containing vessel. A runaway reaction occurs because the rate of reaction, and therefore the rate of heat generation, increases exponentially with temperature. In contrast, the rate of cooling increases only linearly with temperature. Once the rate of heat generation exceeds available cooling, the rate of temperature increase becomes progressively faster. Runaway reactions nearly always result in two-phase flow reliefs. In reactor venting, reactions essentially fall into three classifications ... 

In scale-up, runaway exothermic chemical reactions can be prevented by taking appropriate safety measures. The onset or critical temperature for a runaway reaction depends on the rate of heat generation and the rate of cooling, which are closely linked to the dimensions of the vessel. 

Kata cooling power The rate of cooling of a silvered or unsilvered kata thermometer due to the relationship between the air temperature and the air velocity over the bulb. 

KUhlung, /. cooling, refrigeration. KUhlungagrad, m. degree of cooling rate of cooling. 

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