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Rabinovitch

In the case of polyatomic molecules, one may consider separately the accommodation coefficients for translational and for vibrational energy. Values of the latter, civ, are discussed by Nilsson and Rabinovitch [7]. [Pg.602]

Altkorn R and Zare R N 1984 Effects of saturation on laser-induced fluorescence measurements of population and polarization Annual Review of Physical Chemistry ed B S Rabinovitch, J M Schurr and H L Strauss (Palo Alto, CA Annual Reviews)... [Pg.821]

To detect tlie initial apparent non-RRKM decay, one has to monitor the reaction at short times. This can be perfomied by studying the unimolecular decomposition at high pressures, where collisional stabilization competes with the rate of IVR. The first successful detection of apparent non-RRKM behaviour was accomplished by Rabinovitch and co-workers [115], who used chemical activation to prepare vibrationally excited hexafluorobicyclopropyl-d2 ... [Pg.1035]

The molecule decomposes by elimination of CF, which should occur with equal probabilities from each ring when energy is randomized. However, at pressures in excess of 100 Torr there is a measurable increase in the fraction of decomposition in the ring that was initially excited. From an analysis of the relative product yield versus pressure, it was deduced that energy flows between the two cyclopropyl rings with a rate of only 3x10 s In a related set of experiments Rabinovitch et al [116] studied the series of chemically activated fliioroalkyl cyclopropanes ... [Pg.1036]

Lin Y N and Rabinovitch B S 1970 A simple quasi-accommodation model of vibrational energy transfer J. Rhys. Chem. 74 3151-9... [Pg.1039]

Rabinovitch B S and Setser D W 1964 Unimolecular decomposition and some isotope effects of simple alkanes and alkyl radicals Adv. Photochem. 3 1-82... [Pg.1043]

Rynbrandt J D and Rabinovitch B S 1971 Direct demonstration of nonrandomization of internal energy in reacting molecules. Rate of intramolecular energy relaxation J. Chem. Phys. 54 2275-6... [Pg.1044]

Meagher J F, Chao K J, Barker J R and Rabinovitch B S 1974 Intramolecular vibrational energy relaxation. Decomposition of a series of chemically activated fluoroalkyl cyclopropanes J. Phys. Chem. 78 2535 3... [Pg.1044]

Tardy D C and Rabinovitch B S 1977 Intermolecular vibrational energy transfer in thermal unimolecular systems Chem. Rev. 77 369-408... [Pg.1083]

Figure Bl.26.4. The adsorption of argon and krypton on graphitized carbon black at 77 K (Eggers D F Jr, Gregory N W, Halsey G D Jr and Rabinovitch B S 1964 Physical Chemistry (New York Wiley) eh 18). Figure Bl.26.4. The adsorption of argon and krypton on graphitized carbon black at 77 K (Eggers D F Jr, Gregory N W, Halsey G D Jr and Rabinovitch B S 1964 Physical Chemistry (New York Wiley) eh 18).
Waage E V and Rabinovitch B S 1971 Some aspects of theory and experiment in the ethane-methyl radical system int. J. Chem. Kinetics 3 105-25... [Pg.2149]

Oref I and Rabinovitch B S 1979 Do highly excited polyatomic molecules behave ergodically Acc. Chem. Res. 12 166-75... [Pg.2150]

Flowers M C and Rabinovitch B S 1985 Localization of excitation energy in chemically activated systems. 3-ethyl-2-methyl-2-pentyl radicals J. Rhys. Chem. 89 563-5... [Pg.2150]

Dimethylbut-2-ene [563-79-1 ] M 84.2, b 72-73 /760mra, d 0.708, n 1.41153. Purified by GLC on a column of 20% squalene on chromosorb P at 50° [Flowers and Rabinovitch J Phys Chem 89 563 1985]. Also washed with IM NaOH soln followed by H2O. Dried over Na2S04, distd over powdered KOH... [Pg.214]

Delphinium sp. From an unidentified species of delphinium the following alkaloid was isolated by Rabinovitch and Konovalova. ... [Pg.697]


See other pages where Rabinovitch is mentioned: [Pg.161]    [Pg.676]    [Pg.860]    [Pg.1896]    [Pg.2150]    [Pg.171]    [Pg.510]    [Pg.510]    [Pg.510]    [Pg.510]    [Pg.510]    [Pg.510]    [Pg.510]    [Pg.511]    [Pg.511]    [Pg.382]    [Pg.509]    [Pg.114]    [Pg.129]    [Pg.60]    [Pg.400]    [Pg.48]    [Pg.247]    [Pg.247]    [Pg.772]    [Pg.271]    [Pg.833]    [Pg.1866]    [Pg.109]   
See also in sourсe #XX -- [ Pg.15 , Pg.494 ]




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