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Pyrethrins, general structure

Pyrethroids are a class of synthetic chemicals that are similar in structure to natural pyrethrins. They have been used in field crops and urban pest management for nearly 30 years, and within the last 5 to 10 years new products have been registered for specific use against stored-product insects. Resmethrin is labeled for use as an aerosol in food plants, mills, and warehouse facilities, but could have potential side effects such as discoloration of surfaces and odor contamination and may be more appropriate for use in empty facilities. Labels generally state to cover any food prior to application. The pyrethroids esfenvalerate (Conquer) and prallethrin (Etoc) are also labeled for use in some situations as an aerosol space treatment in... [Pg.270]

In the last century, the development of organophosphorus, carbamate, and organochloride insecticides was followed by synthetic pyrethroids. As a result, pyrethroids are now used frequently in the domestic milieu. Pyrethroid insecticides are synthetically derived from the molecular structure or sharing the same mechanism of action of natural pyrethrins that have broader spectmm of activity, more stability, and residual activity (persists longer than that of natural pyrethrins) and include the following allethrin, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, fenvalerate, flumethrin, fluvalinate, tau-fluvalinate, and permethrin (see structure in Fig. 137.2). They are lipophilic compounds and generally of low acute oral toxicity to mammals but are very toxic to aquatic organisms. When synthetic pyrethroids are administered to mammals parenterally, the synthetic pyrethroids are neurotoxic. [Pg.4672]

Pyrethrum. Pyrethrum is solvent-extracted from the flowers of Chrysanthemum cinerariaefolium and is the most important naturally-occurring insecticide. This variety of chrysanthemum is grown mainly in Kenya but also in Ecuador. Pyrethrum owes its importance to its very rapid knockdown action against a variety of flying insects, e.g. houseflies and mosquitoes, and its low mammalian toxicity. The active ingredients a e a series of structurally similar compounds called pyrethrins, which have the general formula shown below. [Pg.267]

Synthetic analogs of the pyrethrins, pyrethroids, have been widely produced as insecticides during recent years. The first of these was allethrin, and another common example is fenvalerate (see structural formulas in Figure 4.6). Other examples of insecticidal pyrethroids that have water pollution potential include cypermethrin and deltamethrin. Because of the ways that they are applied and their biodegradabilities, these substances generally are not found to be significant water pollutants. [Pg.94]


See other pages where Pyrethrins, general structure is mentioned: [Pg.61]    [Pg.61]    [Pg.27]    [Pg.56]    [Pg.61]    [Pg.247]    [Pg.370]    [Pg.79]   
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General structure

Pyrethrin

Pyrethrins

Pyrethrins Pyrethrin

Pyrethrins structure

Structural generalization

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