Pulsed field nuclear magnetic resonance

Pulse length (nuclear magnetic resonance) Short time during which the magnetic field is applied. 

Nuclear Magnetic Resonance. The iateraction of a nucleus with Bq is usually described usiag vector notation and models as ia Figure 2 where the bulk magnetization, Af, and the static field Bq are initially parallel to A radio frequency pulse is appHed ia the xy plane for a duration of t p.s,... 

W. Brown, R. Johnsen, P. Stilbs, B. Lindman. Size and shape of nonionic amphiphile (Ci2Eg) micelles in dilute aqueous solutions as derived from quasielastic and intensity of light scattering, sedimentation and pulsed-field-gradient nuclear magnetic resonance self-diffusion data. J Phys Chem 87 4548-4553, 1983. 

Hadden, DA, Master of Science Thesis, Florida State University, Tallahassee, FL, 1999. Hadden, D Rill, RL McFadden, L Locke, BR, Oligonucleotide and Water Self-Diffusion in Pluronic Triblock Copolymer Gels and Solutions by Pulsed Field Gradient Nuclear Magnetic Resonance, Macromolecules 33, 4235, 2000. 

While the nuclear magnetic resonance (NMR) technique has widely been used to study diffusion processes of normal liquids, solids, or colloidal systems, there are only a few applications to molten salts. The spin echo self-diffusion method with pulsed field gradients was applied to molten salts by Herdlicka et al. "" There is no need to set up or maintain a concentration gradient. 

W. S. Price 1997, (Pulsed-field gradient nuclear magnetic resonance as a tool for studying translational diffusion Part 1. Basic theory), Concepts Magn. Reson. 9, 299-336. 

U.Tallarek, E. Bayer, G. Guiochon 1998, (Study of dispersion in packed chromatographic columns by pulsed field gradient nuclear magnetic resonance), J. Am. Chem. Soc. 120, 1494. 

P. T. Callaghan, K. W. Jolley, R. S. J. Humphrey 1983, (Diffusion of fat and water in cheese as studied by pulsed field gradient nuclear magnetic-resonance), Colloid Interface Sci. 93, 521. 

Nuclear magnetic resonance spectroscopy Interaction magnetic fields - nuclei Resonance of radiation quanta, h v Radiofrequency pulses Spectrum in time or frequency (FT) domain ... 

Price, W.S. 1998a. Pulsed-field gradient nuclear magnetic resonance as a tool for studying translational diffusion. II. Experimental aspects. Basic theory. Concepts in Magn. Reson. 10, 197-237. Price, W.S. 1998b. NMR imaging. In Annual Reports on NMR Spectroscopy (G.A. Webb, ed.), Vol. 34, pp. 140-216. Academic Press, New York. 

The pulsed field gradient nuclear magnetic resonance (PFG NMR) technique is experimentally distinct from the radiotracer technique but the principle is very similar. A fraction of the nuclei of each constituent is labelled by flipping their spins and monitoring the diffusion of these species. Both techniques are influenced by the presence of neutral associates unlike the Hittorf/Tubandt method. 

Abbreviations MD, molecular dynamics TST, transition state theory EM, energy minimization MSD, mean square displacement PFG-NMR, pulsed field gradient nuclear magnetic resonance VAF, velocity autocorrelation function RDF, radial distribution function MEP, minimum energy path MC, Monte Carlo GC-MC, grand canonical Monte Carlo CB-MC, configurational-bias Monte Carlo MM, molecular mechanics QM, quantum mechanics FLF, Hartree-Fock DFT, density functional theory BSSE, basis set superposition error DME, dimethyl ether MTG, methanol to gasoline. 

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