Pseudoreversible

Fig. 5.4 Pseudoreversibility of an infarct. Sixty-one-year-old with atrial fibrillation, congestive heart failure, and ICA thrombus recanalized with intra-arterial thrombolysis (lAT). (a) Initial CT-CBV demonstrates a large right middle cerebral artery (MCA) territory hypodense region that was outhned by visual...

This half-wave potential is very useful in evaluating the reactant transport-affected electrochemical reaction. Note again that Eqn (2.80) is for the case of reversible reactions. As a rough estimation, this half-wave potential may be useful for those pseudoreversible reactions. However, one should be careful when using this halfwave potential to evaluation the irreversible electrochemical reactions. 

Moir D, Stewart SE, Osmond BC, Botstein D. (1982) Cold-sensitive cell-division-cycle mutants of yeast isolation, properties, and pseudoreversion studies. Genetics 100(4), 547-563. 

As indicated before, the electronic energy levels in the conjugated polymers (as estimated, for instance, from pseudoreversible voltammetric oxidation/reduction currents) are generally distributed over a considerable range. Thus, in order to match voltammetric waves obtained on the basis of Eq. (44) with (quasi-reversible) experimental ones, activity coefficients are necessary... 

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