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Propyl nitrite

Secondary nitro compounds are converted into ketones under very mild conditions using )i-propyl nitrite and sodium nitrite in DMSO. ... [Pg.162]

It forms azeotropic mixts with methylol, carbon disulfide, isopentane, isopropyl halides, isoprene, etc. Prepn is by treating isopropyl ale with nitrosyl chloride. Also, by passing N02 into isopropyl ale at 25—30°. Coml prepn is similar to that of n-propyl nitrite (above). The nitrite has a flash p of < 10°... [Pg.968]

Iso-Propyl nitrite is used as a jet proplnt, a jet proplnt additive and as an additive to diesel fuels... [Pg.968]

Decyl nitrite, 3364 f Ethyl nitrite, 0867 f Isopentyl nitrite, 1996 f Isopropyl nitrite, 1262 f Methyl nitrite, 0455 f Pentyl nitrite, 1998 f Propyl nitrite, 1265... [Pg.46]

The barriers to rotation of esters deserve mention here, especially in comparison to amide barriers. The H NMR spectra of some nitrites (45) were measured in 1957 (83). The temperature had to be lowered to - 58°C at 30 MHz to see the separate signals of propyl nitrite. The barriers to rotation were ca. 10 kcal/mol. This result may be rationalized by considering the lesser electron-donating ability of the alkoxy relative to the dialkylamino group. The dipolar canonical form (46) of nitrite esters is not as stable as that of nitrosamines. [Pg.28]

Propyl nitrite [543-67-9] Sprague-Dawley rats LC50 (4-h) 2.48 Klonne et al., 1987a... [Pg.1386]

Dichlorohydrin-1 -nitrite (called 2.3-Dichlor-propyl-nitrit in Ger), ClH2C.CHCl.CH2O.NO mw 141.99, N 9.8655 ... [Pg.106]

Intramolecular abstraction of hydrogen by the intermediate alkoxy radical B to furnish the alkyl radical C always takes place through a six-membered transition state. In the photolysis of organic nitrites, no exception to this rule of six has been recorded to date. Thus, photolysis of 3-phenyl-l-propyl nitrite does not yield any product corresponding to attack on the a-carbon through a five-membered transition state (90), although abstraction of such a hydrogen should be exothermic to the extent of ca. 25 kcal./mole. 3 Also, irradiation of 5-phenyl-l-pentyl... [Pg.288]

See other pages where Propyl nitrite is mentioned: [Pg.485]    [Pg.299]    [Pg.152]    [Pg.291]    [Pg.968]    [Pg.968]    [Pg.270]    [Pg.299]    [Pg.450]    [Pg.1795]    [Pg.1939]    [Pg.754]    [Pg.340]    [Pg.341]    [Pg.343]    [Pg.373]    [Pg.400]    [Pg.411]    [Pg.9]    [Pg.19]    [Pg.23]    [Pg.25]    [Pg.46]    [Pg.51]    [Pg.52]    [Pg.55]    [Pg.70]    [Pg.70]    [Pg.75]    [Pg.83]    [Pg.85]    [Pg.86]    [Pg.86]    [Pg.90]    [Pg.90]    [Pg.90]    [Pg.97]   
See also in sourсe #XX -- [ Pg.270 ]

See also in sourсe #XX -- [ Pg.348 ]

See also in sourсe #XX -- [ Pg.342 , Pg.349 ]

See also in sourсe #XX -- [ Pg.135 ]



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F Propyl nitrite

Propyl acetate nitrite

Propyl iodides nitrites

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