Pressure Dependence of Boiling Point

Rearrangement of the Antoine equation (7.4.1) leads to the following equation, which permits the estimation of boiling points from known Antoine constants within the applicable range for a given pressure  

Reduced-Pressure Tb-Structure Relationships For certain compound classes, quantitative 7),-structure relationships are available to estimate Tb at reduced pressure. For example, the following equation has been reported by Kreglewski and Zwolinski for n-alkanes (C6-Cis) [6], in analogy to eq. 9.2.1  

Rechsteiner, C. E., Boiling Point, in Handbook of Chemical Property Estimation, W. J. Lyman, W. F. Reehl, and D. H. Rosenblatt, Editors, 1990. Washington, DC American Chemical Society. 

Satayanarayana, K., and P. G. Rao, Improved Equation to Estimate Flash Points of Organic Compounds. J. Hazard. Mater., 1992 32, 81-85. 

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