Polyvinyl alcohol controlled oxidation

Preparation and characterization of PANI/NiO nanocomposite using various surfactants, e.g., polyvinyl alcohol and hydroxypropylcellulose, were reported by Aleahmad et al. [230]. PANl and NiO were electro-codeposited from aniline and NiSO through cyclic voltammetric scans at controlled acidity leading thus to the formation of PANI/NiO composite film [231]. The stability of NiO in the composite films against acidic environments was found to be enhanced in comparison with the corresponding stability of pure NiO. Electrochemical catalytic behavior of PANl/NiO composite film was demonstrated by the catalytic oxidation of methanol and ethanol. Multicolored electrochromic thin films of... 

Mitsubishi Kasei introduced a process to manufacture isononyl alcohol, an important PVC (polyvinyl chloride) plasticizer, via the hydroformylation of octenes (a mixture of isomers produced by dimerization of the C4 cut of naphtha cracker or FCC processes).95 First a nonmodified rhodium complex exhibiting high activity and selectivity in the formation of the branched aldehyde is used. After the oxo reaction, before separation of the catalyst, triphenylphosphine is added to the reaction mixture and the recovered rhodium-triphenylphosphine is oxidized under controlled conditions. The resulting rhodium-triphenylphosphine oxide with an activity and selectivity similar to those of the original complex, is recycled and used again to produce isononanal. 

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