Polyoxometalate liquid phase oxidation

Liquid-phase oxidations catalyzed by polyoxometalates are covered by Mizuno, Kamata, and Yamaguchi (Chapter 13). Finally, the developing field of enantioselective heterogeneous catalysis is presented by Coman, Poncelet, and Parvulescu (Chapter 14). 

Liquid-Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate-Based Compounds... 

Since the application of POMs is so widespread across areas such as homogeneous and heterogeneous catalysis, as well as acid and redox catalysis, it is not possible to exhaustively review all the applications. Thus the rest of this chapter focuses only on the catalytic properties of the polyoxometallates in heterogeneous gas- or liquid-phase oxidation reactions, and reviews the most recent progress in the knowledge of their properties and working process, underlining both their potential and their limitations. 

N. Mizuno, K. Kamata, K. Yamaguchi, in R. Richards (Ed.), Surface and Nanomolecular Catalysis, Taylor and Francis Group, Liquid-phase oxidations catalyzed by polyoxometalates. New York, (2006), p. 463. 

Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates... 

MIL-101 can be utilized for selective catalysis either as the heterogeneous catalyst or the solid support. Kholdeeva s group investigated a series of MIL-101 supported polyoxometalate-based heterogeneous catalyst for selective liquid phase oxidation. ... 

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