Polymer Surface Fluorination with Xenon Difluoride

Xenon difluoride reacts with carbon-carbon single, double, and triple bonds giving addition fluoroorganic compounds, e.g., [Pg.231]

In this respect XeF2 is similar to molecular fluorine. The relatively low oxidizing ability and reactivity ofXeF2 in the same type of chemical reactions is explained by its greater dissociation energy. The activation energy of the dissociation (XeF2- XeF + F) is 190-210 kJ/mol. The XeF radicals are very weakly bound (EXcF = 58-80 kJ/mol) and can be an effective source ofF atoms.3 [Pg.231]

The procedure was a very simple one. The sample and a certain amount of XeF2 were placed together in a stainless steel reactor (V= 6 liters). The reactor [Pg.231]

POLYMER SURFACE FLUORINATION WITH XENON DIFLUORIDE [Pg.231]

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