Polycrystals

Berendsen, H.J.C., Postma, J.P.M., Van Gunsteren, W.F. Statistical mechanics and molecular dynamics The calculation of free energy, in Molecular Dynamics and Protein Structure, J. Hermans, ed.. Polycrystal Book Service, PO Box 27, Western Springs, 111., USA, (1985) 43-46. 

Fine-grained polycrystals Amorphous deposits Gas-phase nucleated snow... 

Y-TZP = yttria-stabilized tetragonal zirconia polycrystal. LAS = lithium alurninosiUcate. 

P.S. Follansbee and G.T. Gray III, The Response of Single Crystal and Polycrystal Nickel to Quasi-Static and Shock Deformation, in Advances in Plasticity 1989 (edited by A.S. Khan and M. Tokuda), Pergamon Press, Oxford, 1989, pp. 385-388. 

The crystals, or grains, in a polycrystal fit together exactly but their crystal orientations differ (Fig. 10.4). Where they meet, at grain boundaries, the crystal structure is disturbed, but the atomic bonds across the boundary are numerous and strong enough that the boundaries do not usually weaken the material. 

Example Approximate calculation of the hardness of solids. This concept of shear yielding - where we ignore the details of the grains in our polycrystal and treat the material as a continuum - is useful in many respects. For example, we can use it to calculate the loads that would make our material yield for all sorts of quite complicated geometries. 

As the stress is reduced, the rate of power-law creep (eqn. (19.1)) falls quickly (remember n is between 3 and 8). But creep does not stop instead, an alternative mechanism takes over. As Fig. 19.4 shows, a polycrystal can extend in response to the applied stress, ct, by grain elongation here, cr acts again as a mechanical driving force but, this time atoms diffuse from one set of the grain faces to the other, and dislocations are not involved. At high T/Tm, this diffusion takes place through the crystal itself, that... 

HJC Berendsen. In I Hermans, ed. Molecular Dynamics and Pi otem Structure. Western Springs, IL Polycrystal Book Service, 1985. 

TEM offers two methods of specimen observation, diffraction mode and image mode. In diffraction mode, an electron diffraction pattern is obtained on the fluorescent screen, originating from the sample area illuminated by the electron beam. The diffraction pattern is entirely equivalent to an X-ray diffraction pattern a single crystal will produce a spot pattern on the screen, a polycrystal will produce a powder or ring pattern (assuming the illuminated area includes a sufficient quantity of crystallites), and a glassy or amorphous material will produce a series of diffuse halos. 

LEED beam is reduced to less than the sample grain size, individual grains in a polycrystal can be investigated. It is difficult to make low-energy electron beams this small, but in some materials large grain sizes can be achieved in polyctystals. 

Kocks, U.F., Tome, C.N. and Wenk, H.-R (1998) Texture and Anisotropy Preferred Orientations in Polycrystals and their Effects on Materials Properties (Cambridge University Press, Cambridge). 

Another new and much used variant is a procedure called orientation imaging microscopy (Adams ci al. 199.5) patterns created by electrons back-scattered from a grain are automatically interpreted by a computer program, then the grain examined is automatically changed, and finally the orientations so determined are used to create an image of the polycrystal with the grain boundaries colour- or thickness-... 

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