Poly 1,4-cyclohexylenedimethylene synthesis

See also PBT degradation structure and properties of, 44-46 synthesis of, 106, 191 Polycaprolactam (PCA), 530, 541 Poly(e-caprolactone) (CAPA, PCL), 28, 42, 86. See also PCL degradation OH-terminated, 98-99 Polycaprolactones, 213 Poly(carbo[dimethyl]silane)s, 450, 451 Polycarbonate glycols, 207 Polycarbonate-polysulfone block copolymer, 360 Polycarbonates, 213 chemical structure of, 5 Polycarbosilanes, 450-456 Poly(chlorocarbosilanes), 454 Polycondensations, 57, 100 Poly(l,4-cyclohexylenedimethylene terephthalate) (PCT), 25 Polydimethyl siloxanes, 4 Poly(dioxanone) (PDO), 27 Poly (4,4 -dipheny lpheny lpho sphine oxide) (PAPO), 347 Polydispersity, 57 Polydispersity index, 444 Poly(D-lactic acid) (PDLA), 41 Poly(DL-lactic acid) (PDLLA), 42 Polyester amides, 18 Polyester-based networks, 58-60 Polyester carbonates, 18 Polyester-ether block copolymers, 20 Polyester-ethers, 26... 

Y. G. Jeong, W. H. Jo, and S. C. Lee. Synthesis and isodimor-phic cocrystallization behavior of poly(l,4-cyclohexylenedimethylene tere-phthalate-co-1,4-cyclohexylenedimethylene 2,6-naphthalate) copolymers. J. Polym. ScL, Part B Polym. Phys., 42(1) 177-187, January 2004. 

Jeong YG, Jo WH, Lee SC. Synthesis and isodi-morphic cocrystallization behavior of poly( 1,4-cyclohexylenedimethylene terephthalate-co-1, 4-cyclohexylenedimethylene 2,6-naphthalate) copolymers. J Polym Sci Part B Polym Phys 2004 42(l) 177-87. 

Jeong YG, Jo WH, Lxe SC. Synthesis and crystallization behavior of poly(m-methylene 2,6-naphthalate-co-1,4-cyclohexylenedimethylene... 

The polycondensation in solution method was also the method applied for the synthesis of poly(l,4-cyclohexylenedimethylene succinate) PCDS referred before (18). The molecular weight of the polymer increased with the boiling point of the solvent employed so highest molecular weights were achieved in n-decane at 215 °C with l-chloro-3-hydroxy-l,l,3,3-tetrabutyldistannoxane as catalyst. 

Figure 6.19 Synthesis of poly[oxy(2-chloro-l,4-phenylene terephthalate-co-1,4-cyclohexylenedimethylene terephthalate) by polycondensation in solution.

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