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Poly allowed side-chain conformations

How adsorption of the side chains to a flat substrate effects the backbone conformation has been observed in further microscopic detail for brush molecules with a methacrylate backbone and poly-(n-butyl acrylate) side chains. These poly(/v-butyl acrylate) brushes were prepared by living radical grafting from a multifunctional macromolecular initiator.38 The synthetic approach allowed observation of the same batch of molecules without (macroinitiator) and with poly(n-butyl acrylate) side chains (brush). [Pg.376]

The various orientations and conformations mesogenic groups can adopt in a layer has been studied extensively for low molar mass smectic materials, and the classification and terminology of smectic systems is entirely based on these studies. However, low molar mass smectic compound or smectic LC-side chain polymers do, of course, not allow one to elucidate the role spacers play in the layer structures of LC-main chain polymers. Therefore, poly(ester-imide)s, po-... [Pg.176]

See other pages where Poly allowed side-chain conformations is mentioned: [Pg.368]    [Pg.937]    [Pg.589]    [Pg.603]    [Pg.17]    [Pg.425]    [Pg.61]    [Pg.71]    [Pg.314]    [Pg.72]    [Pg.125]    [Pg.126]    [Pg.141]    [Pg.396]    [Pg.230]    [Pg.399]    [Pg.13]    [Pg.381]    [Pg.508]    [Pg.611]    [Pg.791]    [Pg.605]    [Pg.160]    [Pg.189]    [Pg.1204]    [Pg.7458]    [Pg.1570]    [Pg.379]    [Pg.380]    [Pg.88]    [Pg.538]    [Pg.430]    [Pg.151]    [Pg.354]    [Pg.442]    [Pg.250]    [Pg.46]    [Pg.288]    [Pg.746]    [Pg.343]    [Pg.567]    [Pg.104]    [Pg.71]    [Pg.65]    [Pg.56]    [Pg.56]    [Pg.209]    [Pg.495]   
See also in sourсe #XX -- [ Pg.318 ]



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Allowables

Allowances

Chain conformation

Poly chain

Poly chain conformation

Poly conformation

Poly conformers

Poly side chains

Side-chain conformations

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