Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Poisson probability relation

If the incoming call distribution is Poisson, and the time to service a call has an exponential distribution (Eq. 11 with density parameter p), then the transitional probabilities related to states s0 (the server is free) and Si (the server is engaged) are Pio= 1 - exp(-pt) poi = 1 -pw> pu= 1 -P o, Pooandpu are found by solving the Kolmogorov equations (Eq. 8)... [Pg.289]

At low overpotentials, the silver electrode prepared according to Budev-ski et al. behaves as an ideal polarized electrode. However, at an overpotential higher than —6 mV the already mentioned current pulses are observed (Fig. 5.48A). Their distribution in the time interval r follows the Poisson relation for the probability that N nuclei are formed during the time interval x... [Pg.384]

It is a random walk over the integers n = 0,1,2,... with steps to the right alone, but at random times. The relation to chapter II becomes more clear by the following alternative definition. Every random set of events can be treated in terms of a stochastic process Y by defining Y(t) to be the number of events between some initial time t = 0 and t. Each sample function consists of unit steps and takes only integral values n = 0,1, 2,... (fig. 5). In general this Y is not Markovian, but if the events are independent (in the sense of II.2) there is a probability q(t) dt for a step to occur between t and t + dt, regardless of what happened before. If, moreover, q does not depend on time, Y is a Poisson process. [Pg.136]

If there is no interaction between similar reactants (traps) B, they are distributed according to the Poisson relation, Ab (r, t) = 1. Besides, since the reaction kinetics is linear in donor concentrations, the only quantity of interest is the survival probability of a single particle A migrating through traps B and therefore the correlation function XA(r,t) does not affect the kinetics under study. Hence the description of the fluctuation spectrum of a system through the joint densities A (r, ), which was so important for understanding the A4-B — 0 reaction kinetics, appears now to be incomplete. The fluctuation effects we are interested in are weaker here, thus affecting the critical exponent but not the exponential kinetics itself. It will be shown below that adequate treatment of these weak fluctuation effects requires a careful analysis of many-particle correlations. [Pg.271]

The three components of the electric field gradient tensor are related by Poisson s equation, as shown earlier. However, the electrons that have a finite probability density at the nucleus, the s and p1/2 electrons, have a spherically symmetric distribution around the nucleus and as such do not contribute to E2. Thus, in the computation of E2, the Un can be related by... [Pg.132]

This probability then has to be multiplied by the probability that one event will happen to occur within the short resolution time interval dt of the measuring device (dt is different from the resolving time At introduced above). According to the fundamental probability of the Poisson distribution, this probability dP for observing one event in an infinitesimally small time interval dt obeys the relation... [Pg.175]

Assuming a Poisson distribution of the electroactive speeies, the enhancement fae-tor can be expressed as a power series of a probabihty funetion which is related to the concentration. At low concentrations the probability of finding more than one molecule in a hemisphere with a radius of the molecular collision distance is nearly zero and / = 1. The factor /, and therefore D, increases noticeably at higher concentrations. [Pg.176]

It is interesting to notice that the current fluctuations mapped as the PDF will be related to the probability of the number of molecules in the tip-substrate gap as a function of solution composition. At a solution concentration of 2 mM for a solution volume of 10 cm for example, the actual occupancy is one molecule. However, the actual occupancy, because of fluctuation, is governed by the Poisson distribution (10),... [Pg.759]

Scale-Free Networks The vertex degree distributions of scale-free networks differ from those of large random networks and many small worid networks, which are Poisson distributed (vide supra). By contrast, scale-free networks described by Barabasi and Albert [182] are nonhomogeneously distributed and follow power laws, such that the probability that a random vertex has degree k is inversely related to a power of vertex degree, i.e.,... [Pg.53]

Gaussian and Poisson distributions are related in that they are extreme forms of the Binomial distribution. The binomial distribution describes the probability distribution for any number of discrete trials. A Gaussian distribution is therefore used when the probability of an event is large (this results in more symmetric bell-shaped curves), whereas a Poisson distribution is used when the probability is small (this results in asymmetric curves). The Lorentzian distribution represents... [Pg.293]

The two can be related using a concept called a Poisson process. From the Wikipedia s article on the Poisson Process In probability theory, a Poisson process is a stochastic process which counts the number of events and the time that these events occur in a given time interval. The time between each pair of consecutive events has an exponential distribution with parameter G the parameter is the occurrence rate per unit time] and each of these inter-arrival times is. .. independent of other... [Pg.247]


See other pages where Poisson probability relation is mentioned: [Pg.256]    [Pg.335]    [Pg.164]    [Pg.351]    [Pg.222]    [Pg.18]    [Pg.548]    [Pg.10]    [Pg.11]    [Pg.161]    [Pg.106]    [Pg.216]    [Pg.440]    [Pg.63]    [Pg.501]    [Pg.106]    [Pg.315]    [Pg.219]    [Pg.196]    [Pg.84]    [Pg.203]    [Pg.90]    [Pg.532]    [Pg.140]    [Pg.64]    [Pg.1]    [Pg.1257]    [Pg.412]    [Pg.716]    [Pg.100]    [Pg.217]    [Pg.347]    [Pg.243]    [Pg.210]   
See also in sourсe #XX -- [ Pg.373 ]




SEARCH



Poisson

Poisson probability

© 2024 chempedia.info