Plutonium processing intermediates

When plutonium-239 is produced from urani-um-238 in a breeder reactor, the process occurs in three steps. In the first step, uranium-238 absorbs a neutron. In the second step, a shortlived intermediate element is made through beta decay. In the third step, the plutonium-239 is produced through beta decay. Write a balanced nuclear equation for each of the three steps. 

Plutonium trifluoride. Plutonium trifluoride can be converted directly to plutonium metal, or it is an intermediate in the formation of PUF4 or PUF4 -PUO2 mixtures for thermochemical reduction, as described in Sec. 4.8. The stabilized Pu(III) solution, produced by cation exchange in one of the Purex process options for fuel reprocessing, is a natural feed for the formation of plutonium trifluoride, as is shown in the flow sheet of Fig. 9.9 [03]. A typical eluent solution from cation exchange consists of 30 to 70 g plutonium/liter, 4 to 5 Af nitric acid, 0.2 Af sulfamic acid, and 03 Af hydroxylamine nitrate. The sulfamic acid reacts rapidly with nitrous acid to reduce the rate of oxidation of Pu(III) to about 4 to 6 percent per day. Addition of ascorbic acid to the plutonium solution just before fluoride precipitation reduces Pu(IV) rapidly and completely to Pu(III). 

Neptunium and protactinium complete the listing of fissile and fertile materials, since these are intermediates in the production of plutonium and U233 from XJ238 thorium. Limited exploratory studies of their solubilities have been carried out primarily in connection with the development of processes for their continuous removal from blanket systems. 

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