Platinate, tetracyano potassium

Fo.s4N10PtC6H12.27 I.8H2O, Platinate, tetracyano-, guanidinium (hydrogen difluoride) (1 2 0.27), hydrate (1 1 8), 21 146 P0.60X2N4P1C4H0.30 3H2O, Platinate, tetracyano-, potassium (hydrogen diftuoride) (1 2 0.30), 21 147... [Pg.210]

The metallic character of the cation-deficient partially oxidized tetracyano-platinate complexes is of considerable interest because of their unusual anisotropic electrical properties. The method used in the preparation of these compounds is a modification of the procedure used by Levy1 and gives a higher yield of pure product than the syntheses previously described in the literature2 5 (only the potassium compound has been reported to date). [Pg.6]

In addition to the partially oxidized tetracyanoplatinates, bis(oxalato)platinate-(II) can be nonstoichiometrically oxidized by chemical oxidants13 to form highly lustrous needlelike crystals containing platinum in the 2.36 oxidation state. These complexes have not been characterized to the extent of the tetracyano-platinate complexes however, the oxalato complexes are reported to be highly conducting.13 The starting material is bis(oxalato)platinate(II), which can be prepared in 30% yields from hexachloroplatinate(lV) and potassium oxalate.9... [Pg.16]

Pt(CN)4K2 Potassium tetracyano-platinate(II), 5 215 [Pt(C2H4)Cl2]2 Tetrachloro(di-ethylene)diplatinum(II), 6 210 [Pt(C2H4)Cl3]K Potassium tri-chloro(ethylene)platinate(II), 6 211, 214... [Pg.261]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

See also in sourсe #XX -- [ Pg.2 , Pg.30 ]

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