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Photochemical reactions alkene photoisomerization

The next three chapters are by Inoue and Mori, Albini, and Rossi, and deal with alkene photoisomerization reactions, the modification of benzylic positions and photochemical aromatic substitution reactions. (E)-2-cyclo-heptenone is produced upon irradiation of the Z-isomer at — 50 °C and can be trapped by cyclopentadiene to afford the adduct 13 [13]. Benzyl-substituted dihydroisoquinolinium derivatives can be used for the photochemical synthesis of tetrahydroisoquinolines. The corresponding... [Pg.8]

The discussion of cis-trans photoisomerization of alkenes, styrene, stilbene, and dienes has served to introduce some important ideas about the interpretation of photochemical reactions. We see that thermal barriers are usually low, so that reactions are very fast. Because excited states are open-shell species, they present new kinds of structures, such as the twisted and pyramidalized CIs that are associated with both isomerization and rearrangement of alkenes. However, we will also see familiar structural units as we continue our discussion of photochemical reactions. Thus the triplet diradical involved in photosensitized isomerization of dienes is not an unanticipated species, given what we have learned about the stabilization of allylic radicals. [Pg.1097]

The scope of photochemical [2 + 2] cycloadditions of enones to alkenes in solution is limited by the failure of most acyclic oc,/ -unsaturated carbonyl compounds to undergo bimolecular reactions in competition with rapid unimolecular cisjtrans photoisomerization. [Pg.906]

Several reviews have been published within the year which are of general relevance to the photoreactions of aromatic compounds. The subjects of these reviews include photochemistry in ionic liquids and in isotropic and anisotropic media, organic synthesis utilizing photoinduced electron-transfer reactions," heteroatom-directed photoarylation processes, photochromism, and photochemical molecular devices. Reviews more directly pertinent to the sections in the present chapter include those of the photoisomerization of five-membered heteroaromatic azoles, the photocycloaddition of benzene derivatives to alkenes, Diels-Alder additions of anthracenes, advances in the synthesis of polycyclic aromatic compounds, diarylethene-based photochromic switches, the photo-Fries rearrangement, and the application of Diels-Alder trapping of photogenerated o-xylenols to the synthesis of novel compounds. " A number of chapters in the two recently published handbooks of photochemistry and photobiology and in the revised edition of the text on photochromism are also pertinent to the current subject matter. [Pg.91]


See other pages where Photochemical reactions alkene photoisomerization is mentioned: [Pg.2]    [Pg.234]    [Pg.174]    [Pg.132]    [Pg.114]    [Pg.61]   
See also in sourсe #XX -- [ Pg.1081 , Pg.1082 , Pg.1083 , Pg.1084 , Pg.1085 , Pg.1086 , Pg.1087 , Pg.1088 , Pg.1089 ]




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Alkenes photoisomerization

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Photoisomerization

Reactions photoisomerization

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