Silicon—phosphorus bonds carbon halides

Other theoretical studies discussed above include investigations of the potential energy profiles of 18 gas-phase identity S 2 reactions of methyl substrates using G2 quantum-chemical calculations," the transition structures, and secondary a-deuterium and solvent KIEs for the S 2 reaction between microsolvated fluoride ion and methyl halides,66 the S 2 reaction between ethylene oxide and guanine,37 the complexes formed between BF3 and MeOH, HOAc, dimethyl ether, diethyl ether, and ethylene oxide,38 the testing of a new nucleophilicity scale,98 the potential energy surfaces for the Sn2 reactions at carbon, silicon, and phosphorus,74 and a natural bond orbital-based CI/MP through-space/bond interaction analysis of the S 2 reaction between allyl bromide and ammonia.17... [Pg.267]

A148. C. T. Mortimer, Reaction Heats and Bond Strengths. Pergamon, Oxford, 1962. 201 pp. Metal-carbon and metal-halide bonds are considered in Chapter 8, and bond strengths in silicon, phosphorus, and sulfur compounds in Chapter 10. [Pg.465]