PHOSPHINE-NICKEL CATALYZED COMPLEX CROSS-COUPLING

Phenylurefbanes, 58, 10 Phosgene, 57, 46 Phosphine, diphenyl-, 56,45 Phosphine-mckcl catalyst, 58, 129 PHOSPHINE-NICKEL CATALYZED COMPLEX CROSS-COUPLING OF GRIG-NARD REAGENTS WITH ARYL AND ALKENYL HALIDES, 58, 127 Phosphine, phenyl-, bis(3-dimethylamino-piopyl)-, 55, 128 Phosphine, triphenyl-, 56, 81 Phosphomum, [ 4-(4-rne thoxy phenyl)-2-butenyl) triphenyl, iodide, 56, 81 Phosphomum, 2-octadecenyltnphenyl-, iodide, 56, 81... 

Asymmetric Grignard Cross-Coupling Catalyzed by Chiral Phosphine-Nickel Complexes 73)... 

More recent review Hayashi, T. Asymmetric Grignard Cross-Coupling Catalyzed by Chiral Phosphine-Nickel and Phosphine-Palladium Complexes, in Asymmetric Reactions and Processes in Chemistry (Eliel, E. L., Otsuka, S. ed.), American Chemical Soc. Symp. Series Vol. 185, p. 177 (1982)... 

Organometallic reagents and catalysts continue to be of considerable importance, as illustrated in several procedures CAR-BENE GENERATION BY a-ELIMINATION WITH LITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE l-ETHOXY-2-p-TOL-YLCYCLOPROPANE CATALYTIC OSMIUM TETROXIDE OXIDATION OF OLEFINS PREPARATION OF cis-1,2-CYCLOHEXANEDIOL COPPER CATALYZED ARYLA-TION OF /3-DICARBONYL COMPOUNDS 2-(l-ACETYL-2-OXOPROPYL)BENZOIC ACID and PHOSPHINE-NICKEL COMPLEX CATALYZED CROSS-COUPLING OF GRIG-NARD REAGENTS WITH ARYL AND ALKENYL HALIDES 1,2-DIBUTYLBENZENE. 

Tamao, K., Sumitani, K., Kiso, Y., Zembayashi, M., Fujioka, A., Kodama, S., Nakajima, I., Minato, A., Kumada, M. Nickel-phosphine complex-catalyzed Grignard coupling. I. Cross-coupling of alkyl, aryl, and alkenyl Grignard reagents with aryl and alkenyl halides general scope and limitations. Bull. Chem. Soc. Jpn. 1976, 49, 1958-1969. 

Tamao, K. Discovery of the cross-coupling reaction between Grignard reagents and C(sp2) halides catalyzed by nickel-phosphine complexes. J. Organomet. Chem. 2002, 653, 23-26. 

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