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Phosphide bridges

X0 complexes, 39 255-265 oxohalides, 39 267-268 oxygen atom transfer, 37 340-341 oxygen donor ligands, 37 311-312 pentafluoride, structure, 27 102 phosphide-bridged complexes, 37 311 phthalocyanine... [Pg.221]

Phosphide-bridged complexes, osmium, 37 311 Phosphinates and phosphinites, reaction with hexafluoroacetone, 30 235 Phosphines, 44 318... [Pg.235]

Carry, A. J. MacLaughlin, S. A. Nucciarone, D. Stereochemistry of Metal Complexes Phosphide Bridging Ligands. In Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis Organic Compounds and Metal Complexes, Verkade, J. G., Quin, L. D., Eds. Methods in Stereochemical Analysis 8 VCH Deerfield Beach, 1987 Chapter 16, pp 559-619. [Pg.482]

Benzonitrile acts as a 6e ligand in [Fe3(y3 NCPh)(C0)g3 and in the butterfly cluster [Fe (y -NCPh) (CO) j 2 phosphide bridged cluster [Fe2(y-H)2(y-PPh2)2(CO)g] undergoes ready intramolecular... [Pg.167]

A phosphide-bridged diplatinum(I) bis-ethylene compound 166 (Scheme 10.73) was made by a ligand exchange reaction from ethylene and a diplatinum(I) carbonyl precursor [122]. The Pt(I)-Pt(I)... [Pg.371]

Scheme 10.73 A phosphide-bridged dipiatinum(i) compound 166, and the proton exchange/C-H bond... Scheme 10.73 A phosphide-bridged dipiatinum(i) compound 166, and the proton exchange/C-H bond...
The reaction between a known phosphide bridging diplatinum(I) compound 174 [132] and [AgOTf] produced a Lewis acid adduct at the Pt(I)-Pt(I) bond (175) (Scheme 10.76) [126]. The coordination of Lewis acid has only minor influence on the Pt-Pt-P core. [Pg.374]

Treatment of the phosphide bridged Pt(ll)/Pd(ll) heterobimetallic compound with [Ag(C104)PPh3] led to the formation of Pt-Pd and Pd-Ag bonds in 223 (Scheme 10.92) [155]. The oxidation states of the Pt and Pd centers do not change during the reaction. [Pg.385]

Two phosphide bridges link Th-Pt in [Op2Th(((-PPh2)2Pt(PMe3)]321 and related derivatives of ZrM (M - Nl, Pd, Pt) 38a 3, ) zpRp324 gy possess metal-metal interactions. Several other reports of metal-metal bonded phosphide bridged complexes have appeared.336,346,356,358,438b,439,443 l,3-diphospha-4-... [Pg.180]

See other pages where Phosphide bridges is mentioned: [Pg.189]    [Pg.311]    [Pg.561]    [Pg.665]    [Pg.3501]    [Pg.3533]    [Pg.442]    [Pg.433]    [Pg.1385]    [Pg.664]    [Pg.3500]    [Pg.759]    [Pg.6057]    [Pg.420]    [Pg.90]    [Pg.356]    [Pg.3947]    [Pg.296]    [Pg.124]    [Pg.251]    [Pg.639]    [Pg.373]    [Pg.231]    [Pg.310]    [Pg.311]    [Pg.312]   
See also in sourсe #XX -- [ Pg.773 , Pg.831 ]



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