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Hexafluoroacetone reaction with

The cyclobutadiene analogue diazadiboretidine reacts with hexafluoroacetone to give a nng expansion product [776] (equation 90) 6-(3-Fluoroaryl)decaborane is formed by alkylation of decaboranyl anion and separation of the two isomers (5- and 6-benzyl) formed by reaction with dimethyl sulfide [777] (equation 91). [Pg.606]

When hexafluoroacetone reacts with amides, urethanes [25], thioamides [26], amidines [27], sulfonamides [28, 29], sulfinainides [20], and f),0-dialkyl-amido-phosphates [27], the correspondmg semiamidals are formed m nearly quantitative yield The thermal stabihty of these adducts toward the retro reaction increases with the nucleophihcity of the ammo compound [5] Many polyfluonnated carbonyl compounds react likewise [22 22] On treatment of ureas [34], thioureas [34], thioamides [26], and C,77 diarylatmdmes [27, 25] first with hexa- fluoroacetone and then with dehydratmg agents, heterodienes are obtamed (equation 4)... [Pg.841]

The reaction of hexafluoroacetone azine with cycloheptatriene at 70 °C provides after 8 days a mixture containing 28% of unchanged azine 290 and products formed by three distinct mechanistic pathways, that is, criss-cross cycloaddition product 294, a bis-ene adduct 295 and its oxidation product 296, and [3+6] cycloaddition leading to diaziridine 297, in the ratio 15 38 7 (Scheme 40) <1995JFC(73)203>. [Pg.409]

Benzo crown ether, 39 115-116 Benzoin, catalytic oxidation scheme, 33 62 Benzonitrile, reaction with hexafluoroacetone, 30 268... [Pg.20]

Bisphosphanorhodium acetylacetonates, reaction with hexafluoroacetone, 30 289 Bis(p-indenyl) zirconium dichloride, 13 9 Bis (polfluoroalkyl) mercurials, 3 340 properties of, 3 343-344 Bis(polyazamacrocycles), production, 45 100 Bis(pyrazoiyl)borato ligands, 42 292... [Pg.26]

P-(Chloro)alkylidenephosphoranes, reaction with hexafluoroacetone, 30 259 Chloroaminocyclotetraphosphazene, isomerization, 21 56... [Pg.46]

Difluoromethyldimethylamine, reaction with hexafluoroacetone, 30 272 Difluoromethylene bisfsulfur pentafluoride), 2 139, 147... [Pg.79]

Fluorodisulfuric acid, salts of, 2 127 Fluoro(fluorosulfuryl) peroxide, 16 138-140 preparation of, 16 138, 139 properties of, 16 139 reactions of, 16 139, 140 Fluoroform, 3 379-380 Fluoroimines, preparation, 33 185 Fluorooximes, reaction with hexafluoroacetone, 30 271... [Pg.107]

Me,N-GaH3 molecule, molecular scattering intensity pattern, 41 186-187 [Me NlPhlC-Li], 37 76-77 Mercaptans, reactions with hexafluoroacetone, 30 274... [Pg.174]

Mercapto compounds, oxidation of, 7 242-243 Mercaptodicyanamides, reaction with hexafluoroacetone, 30 267... [Pg.174]

See other pages where Hexafluoroacetone reaction with is mentioned: [Pg.840]    [Pg.300]    [Pg.481]    [Pg.481]    [Pg.258]    [Pg.410]    [Pg.299]    [Pg.764]    [Pg.5]    [Pg.9]    [Pg.12]    [Pg.14]    [Pg.20]    [Pg.24]    [Pg.24]    [Pg.29]    [Pg.30]    [Pg.68]    [Pg.68]    [Pg.68]    [Pg.68]    [Pg.69]    [Pg.70]    [Pg.76]    [Pg.77]    [Pg.103]    [Pg.113]    [Pg.114]    [Pg.118]    [Pg.118]    [Pg.120]    [Pg.148]    [Pg.148]    [Pg.156]    [Pg.169]    [Pg.175]    [Pg.175]   
See also in sourсe #XX -- [ Pg.1153 ]



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Alcohols, reaction with hexafluoroacetone

Amino-acids reaction with hexafluoroacetone

Carbonyl complexes reaction with hexafluoroacetone

Complexes reactions with hexafluoroacetone

Hexafluoroacetone

Hexafluoroacetone reactions

Peroxides, reaction with hexafluoroacetone

Phosphites, reaction with hexafluoroacetone

Phosphorus compounds, reactions with hexafluoroacetone

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