Phenylsilanes, silicon-hydrogen bond

Table V. Silicon-Hydrogen and Carbon-Hydrogen Bond Dissociation Enthalpies in Phenylsilanes and Phenylmethanes Data in kJ/mol...

The silyl halides can now" be prepared in high purity and high yield by the facile hydrogen halide cleavage of the carbon-silicon bond in arylsilanes. " No catalyst is required, and the use of the hazardous intermediate reagent, silane, is avoided. Bromosilane is prepared by the reaction of hydrogen bromide and phenylsilane. The latter is obtained by lithium hydro-aluminate reduction of the commercially available phenyltri-chlorosilane. lodosilane can be prepared in a similar fashion however, mixtures of iodosilane and benzene are difficult to separate. The preferred alternative procedure described below utilizes an isomeric mixture of 2-, 3-, and 4-chlorophenylsilanes as the intermediate. This intermediate is obtained by the chlorination of phenyltrichlorosilane, and is then reduced to the hydride. 

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