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Persistence vector

Figure 15. The mean trajectories of amylosic chains based on the rigid residue (filled circles) and relaxed residue (open circles) models projected into the XY plane of a coordinate system attached to a terminal residue. Circles represent the mean positions of successive glycosidic oxygens in the primary sequence. The persistence vector (mean end-to-end vector) for a chain of x residues is the vector (not shown) connecting the origin and the mean position of the glycosidic oxygen separated from it along the chain by x virtud bonds. Figure 15. The mean trajectories of amylosic chains based on the rigid residue (filled circles) and relaxed residue (open circles) models projected into the XY plane of a coordinate system attached to a terminal residue. Circles represent the mean positions of successive glycosidic oxygens in the primary sequence. The persistence vector (mean end-to-end vector) for a chain of x residues is the vector (not shown) connecting the origin and the mean position of the glycosidic oxygen separated from it along the chain by x virtud bonds.
RIS theory provides a relatively simle formalism for the evaluation of the persistence vector, a, for a chain that can be represented by a repeating sequence of independent virtual bonds such as polybenzobisoxazole (PBOI and polybenzobisthiazole IPBT). The present study combines RIS theory with long molecular dynamics simulations for small fragments in order to evaluate the limiting length of a for very stiff chains. The approach can be applied to other stiff chain polymers. [Pg.347]

A third striking feature of the results for tails is the divergence of the persistence vector a=. This arises because the x-component of the persistence vector is divergent. A comparison is presented in Table 4.2 of the effects of intramolecular excluded volume with that due to an interface. It is apparent that the two different types of excluded volume exert different effects on the conformation of the polymer chain. [Pg.78]

Persistence vector, characteristic ratio and Kuhn step length... [Pg.271]

The persistence vectors vividly portray the correlations between bonds of the chain. These correlations are due to the combined effects of narrowly restricted bond angles, preferences for one or more rotational states over others and the interdependence of rotations about neighboring bonds. The persistence of a freely jointed chain is just the first bond. Transverse components are necessarily null. [Pg.279]

Figure 9 (a) Coordinate system for the persistence vector defined by the first two bonds of a chain (reproduced by permission of Pergamon Press from P. J. Flory, Pure AppL Chem., 1980, 52, 241), (b) Fully extended chain conformation without distortion of bond angles or deformation of bond lengths / is a bond vector and /p its projection on the chain axis... [Pg.280]

A persistent idea is that there is a very small number of flavor quaUties or characteristics, called primaries, each detected by a different kind of receptor site in the sensory organ. It is thought that each of these primary sites can be excited independently but that some chemicals can react with more than one site producing the perception of several flavor quaUties simultaneously (12). Sweet, sour, salty, bitter, and umami quaUties are generally accepted as five of the primaries for taste sucrose, hydrochloric acid, sodium chloride, quinine, and glutamate, respectively, are compounds that have these primary tastes. Sucrose is only sweet, quinine is only bitter, etc saccharin, however, is slightly bitter as well as sweet and its Stevens law exponent is 0.8, between that for purely sweet (1.5) and purely bitter (0.6) compounds (34). There is evidence that all compounds with the same primary taste characteristic have the same psychophysical exponent even though they may have different threshold values (24). The flavor of a complex food can be described as a combination of a smaller number of flavor primaries, each with an associated intensity. A flavor may be described as a vector in which the primaries make up the coordinates of the flavor space. [Pg.3]

Dieldrin [60-57-1] or l,2,3,4,10,10-hexachloro-l,4,4t ,5,8,8t -hexahydro-6,7-epoxy-l,4- <7o, Aro-5,8-dimethanonaphthalene (34) (mp 176°C, vp 0.4 mPa at 20°C) is formed from aldrin by epoxidation with peracetic or perben2oic acids. It is soluble in water to 27 / g/L. Aldrin and dieldrin have had extensive use as soil insecticides and for seed treatments. Dieldrin, which is very persistent, has had wide use to control migratory locusts, as a residual spray to control the Anopheles vectors of malaria, and to control tsetse flies. Because of environmental persistence and propensity for bio accumulation, registrations in the United States were canceled in 1974. [Pg.277]

The small adeno-associated virus (AAV) vectors can be easily prodnced, have not been found to canse major toxicity, and persist in the transduced hepatocyte typically as an episomal transcriptionally active DNA molecule. Because of the limited packaging capacity for foreign DNA of 4.6 kb, these vectors have been preferentially nsed to express small transgenes and shRNAs directed against HBV or HCV... [Pg.270]

The cyclodiene insecticides aldrin, dieldrin, endrin, heptachlor, endosulfan, and others were introduced in the early 1950s. They were used to control a variety of pests, parasites, and, in developing countries, certain vectors of disease such as the tsetse fly. However, some of them (e.g., dieldrin) combined high toxicity to vertebrates with marked persistence and were soon found to have serious side effects in the field, notably in Western European countries where they were extensively used. During the 1960s, severe restrictions were placed on cyclodienes so that few uses remained by the 1980s. [Pg.102]

Chile. It is transmitted by aphids. The virus is not persistent in the aphid vector and only... [Pg.567]

In this way, we can relate duality to quark-hadron continuity. We considered duality, which is already present at zero chemical potential, between the soliton and the vector mesons a fundamental property of the spectrum of QCD which should persists as we increase the quark chemical potential. Should be noted that differently than in [42] we have not subtracted the energy cost to excite a soliton from the Fermi sea. Since we are already considering the Lagrangian written for the excitations near the Fermi surface we would expect not to consider such a corrections. In any event this is of the order //, [42] and hence negligible with respect to Msoiiton. [Pg.156]


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See also in sourсe #XX -- [ Pg.78 ]




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