Perchlorate reaction

Hertz—Knudsen—Langmuir equation, 21 hexammine nickel perchlorate, reaction + H20, 84 holes, 5, 32... 

Electrochemical oxidation of epoxides in absence of nucleophiles, catalyses a rearrangement to the carbonyl compound. The electrolyte for this process is dichlo-romethane with tetrabutylammonium perchlorate. Reaction, illustrated in Scheme 8.7, involves the initial formation of a radical-cation, then rearrangement to the ketone radical-cation, which oxidises a molecule of the substrate epoxide. The process is catalytic and requires only a small charge of electricity [73]. 

Cationic Polymerization. The functional groups that enable initiation of cationic polymerization can be introduced on the inorganic surface. The introductions of acylium perchlorate Reaction (5), sulfonium or pyridinium salt, or active chloride... 

SAFETY PROFILE A poison by subcutaneous route. Questionable carcinogen with experimental tumorigenic data. Catalyzes the potentially explosive polymerization of ethylene oxide. Explosive reaction when heated with guanidinium perchlorate. Reaction with carbon monoxide may form an explosive product. Potentially violent reaction with hydrogen peroxide. 

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