Partition coefficient real chain

The partition coefficient for a real chain (excluded volume chain) has not been obtained except by the scaling theory [6]. The theory gives only a qualitative relationship between K and N for chains sufficiently longer than the pore size Rg Rp) ... 

Figure 2.66. Partition coefficients of a Gaussian chain (solid line) and a real chain (circles) with a radius of gyration in a slit of width d. The data for the real chain were obtained in the computer simulation (From Ref. 5).

Figure 2.67. Sketch of the partition coefficients of a real chain as a function of the number of blobs, AI/ d. In linear scale (a) and in semi-logarithmic scale (b) of M/wj. The shaded region in (b) indicates a nearly straight portion of the plot.

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