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The results presented in this paper strongly suggest that, at the present moment, the most efficient and sufficiently accurate approach for calculating 19F NMR shielding values in fluorobenzenes and other related molecules is a HF-GIAO calculation on top of a ground-state geometry optimized at the MP2 level of theory. 

Indicator papers frequently aid in the identification of chemicals. Strong mineral acids are acid towards methyl violet or thymol blue papers, moderately strong acids react acid towards Congo paper, and very weak acids are acid towards htmus and azolitmin paper. Strong bases show an alkaline reaction with turmeric or tropeolin 0 paper, medium strong bases with phenol-phthalein, and very weak bases with litmus or azolitmin paper. These papers are not recommended for use in quantitative analysis. ... 

The charts arrived at in this maimer have been analyzed by Bertz [19] in a paper strongly recommended for careful reading [cf also 17], Bertz adds the complexities of all intermediates along a synthesis to give the overall complexity. One is not surprised to hnd that the higher the overall complexity, the lower is the overall yield This mirrors common experience. Again, the bottom-hne is avoid refunctionalization steps once the complexity of the intermediates has become high. 

In this paper, we have exposed a solution to improve the resolution in Low Frequency Ultrasonic Tomography. Since the basic principle of ultrasonic reflection tomography prohibits the inspection of objects with strong contrast and large extension, we turn down the frequency of the transducer, in order to increase the penetration length of the wave and the validity of the method. But this is done at the expense of resolution. 

Method 1. From ammonium chloroplatinate. Place 3 0 g. of ammonium chloroplatinate and 30 g. of A.R. sodium nitrate (1) in Pyrex beaker or porcelain casserole and heat gently at first until the rapid evolution of gas slackens, and then more strongly until a temperature of about 300° is reached. This operation occupies about 15 minutes, and there is no spattering. Maintain the fluid mass at 500-530° for 30 minutes, and allow the mixture to cool. Treat the sohd mass with 50 ml. of water. The brown precipitate of platinum oxide (PtOj.HjO) settles to the bottom. Wash it once or twice by decantation, filter througha hardened filter paper on a Gooch crucible, and wash on the filter until practically free from nitrates. Stop the washing process immediately the precipitate tends to become colloidal (2) traces of sodium nitrate do not affect the efficiency of the catalyst. Dry the oxide in a desiccator, and weigh out portions of the dried material as required. 

This solution may also be employed in the test for bromine. If iodine has been found, add small amounts of sodium nitrite solution, warm shghtly and shake with fresh 1 ml. portions of carbon tetrachloride until the last extract is colourless boil the acid solution until no more nitrous fumes are evolved and cool. If iodine is absent, use 1 ml. of the fusion solution which has been strongly acidified with glacial acetic acid. Add a small amount of lead dioxide, place a strip of fluorescein paper across the mouth of the tube, and warm the solution. If bromine is present, it will colour the test paper rose-pink (eosin). 

This short paper describes a modification to the traditional Gran plot for determining the concentration of a weak acid in the presence of a strong acid. 

Titanium Tetrachloride. The major use for titanium tetrachloride [7550 5-0] is in titanium dioxide production, and titanium dioxide [13463-67-7] is enjoying strong growth for use as a filler in pulp and paper manufacture and as a pigment in paint and plastic manufacture. Annual growth for this product is forecasted at between 2.5 and 3.0% through 1992. 

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