Palladium schematic illustration

Fig. 33. Schematic illustration of potential CO hydrogenation routes on palladium catalysts.

Fig. 49. Schematic illustration of CH3OH decomposition and oxidation on palladium surfaces.

I ig- 4.17. Schematic illustration of the structural properties and the CO oxidation mechanism of palladium, zirconia catalyst derived by in situ activation from glassy PdjjZr, precursor... 

Fig. 6.1 (a) Schematic illustration of thiocholine-stabilized palladium nemopaiticles. 

Figure 1. a. Illustration of the dipole layer formed at the palladium Silicon dioxide interface as a result of H interactions b. Schematic capacitance versus applied volt- age, (C-V), and parallel conductance at frequency 6 versus applied voltage, (G- V), for an n-type silicon based Pd MOSCAP in the presence of oxygen (solid line) and hydrogen (dashed line). 

The higher reactivity of nickel complexes than the palladium congeners was examined theoretically. Fig. 9.1 illustrates a schematic diagram for the orbital correlation on the ethane elimination from cw-M(CH3)2(PH3)2 complexes (M = Ni, Pd) [8,10]. This scheme presumes the least motion process that maintains the C2v symmetry of precursor complex throughout the reaction. The C-M-C angle becomes narrow while the P-M-P angle is gradually extended as the reductive elimination proceeds. Finally, ethane is eliminated with formation of a linear M(PH3)2 complex. 

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