Palladium complexes crystal structure

Palladium, polymethylenebis(diphenylphosphine)-bis(thiocyanato)-linkage isomers, 1, 185 Palladium, tetraammine-tetrachloropalladate history, 1, 2 Palladium, tetrachloro-crystal structure, 1, 16 Palladium, tris(dinitrogen)-synthesis, 1,28 Palladium complexes a,(5-dione dioximates electrical properties, 6, 143 acetylacetone hydrolysis, 2,379 alkylperoxo... 

Regioselective addition of ammonia, primary or secondary amines and aniline to neutral 77 -allenylpalladium(ii) complexes /ra/ .y-[PdX(77 -CH=C=CH2)(PPh3)2] gives the respective ry -azatrimethylenemethane complexes trans-[PdX 77 -CH2C(NR R )CH2 (PPh3)2)]X, 44 (Scheme 10). These ry -A-TMM palladium complexes have structural characteristics between those of 77 -aminoallyl and metallacyclobutanimine complexes, as evidenced by several X-ray crystal structures. ... 

Ellis, J.W., Harrison, K.N., Hoye, P.A.T., Orpen, A.G., Pringle, P.G., and Smith, M.B., Water-soluble tris(hydroxymethyl)phosphine complexes with nickel, palladium, and platinum. Crystal structure of Pd P(CH2OH)3 4].cntdot.CH3, Inorg. Chem., 31, 3026, 1992. 

Although lithiation remains the most frequently used metalation reaction, there have been a number of new reports of direct palladation of aryloxazolines. For example, Smoliakova and co-workers prepared the dimeric palladium complex 457 by direct reaction of Pd(OAc)2 with 2-phenyloxazoline in the presence of NaOAc/ HOAc (Scheme 8.150). ° The dimeric complex 457 was converted to the monomeric triphenylphosphine complex 458 for which the X-ray crystal structure was determined. A similar reaction sequence was observed for naphthalenes. Muller... 

A crystal structure determination for this compound showed that while the square planar coordination of palladium is retained, strain within the molecule is relieved by a folding of the ligand239 similar to that described above for salicylaldimine complexes. The fl position of these ligands may be substituted by electrophilic reagents before or after complexation.282... 

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