Palladium clusters oxygen

L. Piccolo, C. Becker, and C.R. Henry. Reaction between CO and a Pre-adsorbed Oxygen Layer on Supported Palladium Clusters. Appl. Surf. Sci., 164 156-162,2000. 

Conjugated aldehydes. Allylic alcohols are converted to enals when treated with either palladium cluster complexes or Ru-Al-Mg hydrotalcites" under molecular oxygen. 

Palladium clusters have been reported to catalyze the oxidative acetoxy-lation of alkenes Propene reacts with acetic acid and oxygen to give allyl acetate according to... 

In their flow tube reactor studies, Hintz and Ervin found that Pt and Pd cluster anions react with molecular oxygen under addition of multiple O2 units [416]. Whereas no monoxide formation is detected, increasing palladium cluster fragmentation with cluster size is observed upon reaction with O2 (loss of metal atoms for Ptg and Pt4 ). The observation of cluster fragmentation... 

Ebitani, K., Fujie, Y. and Kaneda, K. (1999). Immobilization of a Ligand-Preserved Giant Palladium Cluster on a Metal Oxide Surface and its Nobel Heterogeneous Catalysis for Oxidation of AUylic Alcohols in the Presence of Molecular Oxygen, Langmuir, 15, pp. 3557—3562. 

Kenneth and Steve Shoulders report an experiment in which a previously deuteron-loaded palladium cathode was subjected to the impact of a charge cluster [22]. Where the charge cluster impacted the deuteron-loaded palladium a visually-evident, explosive-like reaction occurs (Fig. 8). The palladium cathode was then subjected to an X-ray analysis of the impact crater (see chart in Fig. 8). Typically, the X-ray analysis shows a considerable number of elements not seen when scanning the nearby palladium surface. Such elements as oxygen, calcium, silicon, and magnesium are detected in the exploded region where a charge cluster impacted the palladium. 

NLO properties, 12, 771 from oxygenated ligands, 6, 842 with palladium, 8, 213 and Rh Cp complexes, 7, 160 trinuclear clusters, overview, 6, 835-871 Osmium complexes... 

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