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Palladium-catalyzed hydrophosphorylation

R = n-CeHia, Ph, p-Tol, NC(CH2)a, HC=C(CH2)5, 3-HC=C-C6H4, 1-cyclohexenyl, SiMea Scheme 5-17 Palladium-catalyzed hydrophosphorylation of alkynes... [Pg.154]

Han, L.-B., Mirzaei, F., Zhao, C.-Q., and Tanaka, M., High reactivity of a five-membered cyclic hydrogen phosphonate leading to development of facile palladium-catalyzed hydrophosphorylation of alkenes, /. Am. Chem. Soc., 122, 5407, 2000. [Pg.144]

Zhao Ch-Q, Han L-B, Tanaka M (2000) Palladium-catalyzed hydrophosphorylation of allenes leading to regio- and stereoselective formation of allylphosphonates. Organometallics 19 4196-4198... [Pg.258]

Scheme 5-20 Proposed mechanism for palladium-catalyzed bis-hydrophosphorylation of alkynes... Scheme 5-20 Proposed mechanism for palladium-catalyzed bis-hydrophosphorylation of alkynes...
Allen A Jr, Manke DR, Lin W (2000) Synthesis of functional bisphosphonates via new palladium-catalyzed bis-hydrophosphorylation reactions. Tetrahedron Lett 41 151-154... [Pg.258]

Zhao Ch-Q, Han L-B, Goto M, Tanaka M (2001) Rhodium-catalyzed hydrophosphorylation of terminal alkynes leading to highly selective formation of (i )-afkenylphosphonates complete reversal of regioselectivity to the palladium-catalyzed counterpart. Angew Chem Int Ed 40 1929-1932... [Pg.258]

Ananikov VP, Khemchyan LL, Beletskaya IP (2009) Celebrating 20 years of SYNLETT— special essay general procedure for the palladium-catalyzed selective hydrophosphorylation... [Pg.258]

Xu Q, Han L-B (2006) Palladium-catalyzed asymmetric hydrophosphorylation of norbomenes. Org Lett 8 2099-2101... [Pg.258]

Hydrophosphorylation of alkenes and alkynes with phosphinic acid derivatives such as alkyl phosphinates [H2P(0)(0R)] and anilinium phosphinate [PhNH3 0P (0)H2] is successfully catalyzed by palladium complexes, in particular those ligated by xantphos and dppf [25]. Polymer-botmd palladium catalyst 11 has proved to catalyze the same reactions with phosphinic acid to give good yields, although the... [Pg.176]

Gulykina NS, Dolgina TM, Bondarenko GN, Beletskaya IP (2003) Hydrophosphorylation of terminal alkynes catalyzed by palladium. Russ J Org Chem 39 797-807... [Pg.257]

See other pages where Palladium-catalyzed hydrophosphorylation is mentioned: [Pg.153]    [Pg.109]    [Pg.144]    [Pg.146]    [Pg.186]    [Pg.37]    [Pg.190]    [Pg.306]    [Pg.153]    [Pg.192]    [Pg.257]    [Pg.153]    [Pg.109]    [Pg.144]    [Pg.146]    [Pg.186]    [Pg.37]    [Pg.190]    [Pg.306]    [Pg.153]    [Pg.192]    [Pg.257]    [Pg.1470]   
See also in sourсe #XX -- [ Pg.153 ]

See also in sourсe #XX -- [ Pg.153 ]



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Hydrophosphorylation

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