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P,N donor

The coordinatively flexible P/N-donor ligand PNra (411) reacts with [IrCl(cod)]2 in the presence of AgPFg to yield [Ir(cod)(PNra)](PF6), (412).665 The X-ray structure of (412) PN =i, R = H, complex confirms the cis geometry of the ligand attached via N and P donor atoms to a square-pyramidal Ir1 cod fragment with a long ethereal oxygen—Ir bond in an apical position. The Ir1... [Pg.223]

Six-member P,N donor chelating ligands have been profusely used in coordination chemistry and catalysis. The simplest ligands of these series are the derivatives P(o-phosphino-iV,iV-dimetylbenzylamine) Ph3 (labeled PNi, PN2 and PN3). The successive substitution of phenyl by benzylamine groups at the phosphorus slows down noticeably the conformational inversion. [Pg.144]

Ligands prepared for palladium-catalysed allylation comprised a novel class of bidentate chiral P.N donor ligands based on cinchona alkaloids... [Pg.57]

A series of Pd(I)-Pd(I) compounds (105-111) bearing bidentate P, P- or P, N-donor ligand were synthesized and characterized recently, ofwhich the Pd(I) -Pd(I) bondlength and references arelisted... [Pg.356]

See other pages where P,N donor is mentioned: [Pg.146]    [Pg.10]    [Pg.344]    [Pg.1610]    [Pg.70]    [Pg.539]    [Pg.6]    [Pg.686]    [Pg.295]    [Pg.56]    [Pg.116]    [Pg.151]    [Pg.152]    [Pg.156]    [Pg.170]    [Pg.2696]    [Pg.4764]    [Pg.119]    [Pg.27]    [Pg.4763]    [Pg.295]    [Pg.172]    [Pg.13]    [Pg.436]    [Pg.134]    [Pg.241]    [Pg.630]    [Pg.355]    [Pg.465]    [Pg.530]    [Pg.207]    [Pg.1]    [Pg.351]    [Pg.352]    [Pg.356]   
See also in sourсe #XX -- [ Pg.134 ]



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N donors

P donor

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