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N-Donors

Alkyl groups which are para to strong n-donor substituents such as hydroxy or ... [Pg.600]

The coordination number of Ni rarely exceeds 6 and its principal stereochemistries are octahedral and square planar (4-coordinalc) with rather fewer examples of trigonal bipyramidal (5), square pyramidal (5), and tetrahedral (4). Octahedral complexes of Ni arc obtained (often from aqueous solution by replacement of coordinated water) especially with neutral N-donor ligands such as NH3, en, bipy and phen, but also with NCS, N02 and the 0-donor dimethylsulfoxide. dmso (Me2SO). [Pg.1157]

The nitrogen atom in ri -pyrrolylmanganesetricarbonyl forms a donor-acceptor bond with transition metals. Complexes in which the pyrrolyl ring behaves as a tt ligand for the manganese atom and n-donor for the other metal were synthesized 12 (M = Mn, Re) [78JOM(157)431]. The binuclear heterobimetallic complexes... [Pg.119]

Compounds that are O- and N-donors like oxalate and ethylenediamine are able to support the +6 oxidation state... [Pg.70]

Complexes of other N-donors A range of pyridine complexes can be made [98]... [Pg.121]

Platinum(IV) forms complexes with a range of ligands [1, 2, 10, 11]. 3.10.1 Complexes of N-donors... [Pg.250]

Compounds with N-donor ligands tend to be more stable and not to undergo reductive elimination ... [Pg.266]

Complexes of lanthanide ions with N-donor ligands. J. H. Forsberg, Coord. Chem. Rev., 1973,10, 195-226 (129). [Pg.32]

Wanzlick showed that the stability of carbenes is increased by a special substitution pattern of the disubstituted carbon atom [12-16]. Substituents in the vicinal position, which provide n-donor/a-acceptor character (Scheme 2, X), stabilize the lone pair by filling the p-orbital of the carbene carbon. The negative inductive effect reduces the electrophilicity and therefore also the reactivity of the singlet carbene. [Pg.2]

Scheme 2 Stabilization by vicinal substituents with n-donor/a-acceptor character... Scheme 2 Stabilization by vicinal substituents with n-donor/a-acceptor character...
See other pages where N-Donors is mentioned: [Pg.396]    [Pg.201]    [Pg.169]    [Pg.48]    [Pg.49]    [Pg.676]    [Pg.679]    [Pg.325]    [Pg.430]    [Pg.540]    [Pg.724]    [Pg.958]    [Pg.995]    [Pg.998]    [Pg.1092]    [Pg.1246]    [Pg.1247]    [Pg.118]    [Pg.114]    [Pg.120]    [Pg.121]    [Pg.289]    [Pg.111]    [Pg.122]    [Pg.147]    [Pg.201]    [Pg.285]    [Pg.290]    [Pg.292]    [Pg.302]    [Pg.302]    [Pg.12]    [Pg.149]    [Pg.167]    [Pg.212]   
See also in sourсe #XX -- [ Pg.79 , Pg.80 , Pg.81 ]



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Activation by n Donors (X and C Substituents)

Anionic N-donors

As a n Donor

Clusters containing edge-bridging N-donor ligands

Clusters containing face-bridging N-donor ligands

Complexes of N-Donors

Complexes of Other N-Donors

Cp2LnX compounds with amide and related N-donor ligands

Disubstituted-1,2,3-Triazoles as Monodentate N-Donor Ligands

Dynamic Behavior of d Transition Metal Complexes with n-Donor Two-Center Ligands

Heterocyclic N-donor ligands

Iron carbonyls containing S- and N- or P-donor ligands

Ligands N-donor

Metal Nanoparticles with the Associates of Donor Defects in Wide-Band-Gap n-type Semiconductors

Mixed O,N donors

N -Electron donors

N donor macrocycles

N,O-donor ligands

N- and O-Donor Ligands

N- and O-donors

N- and S-Donor Ligands

N-, NO-, As-, and P-Donor Ligands

N-Donor Adducts of Dimethylzinc

N-H hydrogen-bond donors

N-donor complexes

N-donor two-center

Other N-Donors

Other N-donor ligands

P,N donor

Polydentate N,S Donor Ligands

Redox transformations of N-donor ligands

Ru(III) Complexes with N-Donors

Ru(IV) Complexes with O- or N-Donors

Simple N-Donor Ligands

Synthesis of N-Troc Sialyl Donor

Which B is a n-Pair Donor

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