Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

P-Chlorobenzoyl Peroxide

Chemical Designations - Synonyms Bis-(p-chlorobenzoyl)peroxide p-Chlorobenzoyl Peroxide p,p -Dichlorobenzoyl Peroxide Di-(4-chlorobenzoyl)peroxide Cadox PS Chemical Formula (p-ClCsH COOIj. [Pg.114]

Biphenyl-Diphenyl Ether Bis(Acetato)Dioxouranium Bis(2-Aminoethyl)Amine N, N-Bis(2-Aminoethyl) Ethylenediamine Bis(P-Chlorobenzoyl) Peroxide Bis(2-Chloroethyl) Ether Bis(2-Chloroethyl) Ether Bis(Dimethylthiocarbamyl) Disulfide Bis(Dimethylthiocarbamyl) Disulfide Bis(2-Ethylhexyl) Hydrogen Phosphate Bis-(2-Ethylhexyl)Hydrogen Phosphate Bis(2-Ethylhexyl) Phthalate Bis(2-Ethylhexyl)Sodium Sulfosuccinate Bis(2-(2-Hydroxyethoxy)Etlryl) Ether... [Pg.26]

Compound Name Cadmium Nitrate Cadmium Oxide Cadmium Sulfate Cyclohexanone Peroxide DI-(p-Chlorobenzoyl) Peroxide Tert-Butyl Hydroperoxide Aluminum Sulfate Calcium Phosphate Calcium Resinate... [Pg.31]

Di(m-cblorobenzoyl) Peroxide, crysts (from hydrocarbon solvs), mp 123° dec was prepd by reaction 3 chlorobenzoyl chloride in dry toluene with an excess of aq Na2 2 (Ref 4) Di(p chlorobenzoyl) Peroxide, crysts (from CS2), mp 142°dec explodes in a steel bomb when heated to 180° giving 4-4 -dichlorodiphenyl,... [Pg.102]

Decomposition of Aromatic Acyl Peroxides. The decomposition of aromatic acyl peroxides in liquid aromatic compounds is similar to the decomposition of nitrosoacetylarylamines and appears to involve the intermediate formation of free radicals. When dibenzoyl peroxide is heated in benzene, biphenyl, benzoic acid, and small amounts of phenyl benzoate, p-terphenyl, and quaterphenyl are produced. 4 That the second component enters into the reaction is shown by the formation of 4-chlorobiphenyl from the decomposition of di-p-chlorobenzoyl peroxide in benzene 84 and of dibenzoyl peroxide in-chlorobenzene 86... [Pg.241]

Figure 2.20. Rates of catalysed and uncatalysed polymerisation of styrene at different temperatures. Catalysts used (all at 0.0133 moleA). A, bis-(2,4-dichlorobenzoyl) peroxide B, lauroyl peroxide C, benzoyl peroxide D, bis-(p-chlorobenzoyl) peroxide E, none. (After Boundy and Boyer )... Figure 2.20. Rates of catalysed and uncatalysed polymerisation of styrene at different temperatures. Catalysts used (all at 0.0133 moleA). A, bis-(2,4-dichlorobenzoyl) peroxide B, lauroyl peroxide C, benzoyl peroxide D, bis-(p-chlorobenzoyl) peroxide E, none. (After Boundy and Boyer )...
Di- (P- Chlorobenzoyl) Peroxide Bis- (P-Chloro benzoyl) Peroxide p-Chlorobenzoyl Peroxide P, F-Dichloro-benzoyl Peroxide Di-(4-chlorobenzoyl) Peroxide Cadox Ps... [Pg.242]

Di- (P-Chlorobenzoyl) Peroxide Data not available Not pertinent Data not available Not pertinent... [Pg.382]

CADOX HDP (78-18-2) see 1-hydroxy-l -hydroperoxy dicyclohexyl peroxide. CADOX PS (94-17-7) see p-chlorobenzoyl peroxide. [Pg.197]

DI-(4-CHLOROBENZOYL) PEROXIDE or DI-(p-CHLOROBENZOYL) PEROXIDE or p,p -DICHLOROBENZOYL PEROXIDE (94-17-7) Explosive solid or paste. Thermally unstable above 80°F/27 C explosion can be caused by exposure to direct sunlight, hot surfaces, or heat abovel00°F/38°C. Highly toxic chlorinated biphenyls are emitted in fire. A powerful oxidizer. Reacts violently with many materials, including reducing agents, combustible materials, metallic powders, organic substances, polymerization initiators, thiocyanates, or contaminants. Explosive polymerization may be initiated by shortwave radiation. [Pg.398]

Dicumyl peroxide (cumyl peroxide cumene peroxide, diisopropylbenzene peroxide bis(a,a-dimethylbenzyl)per-oxide] [80-43-3] Bis(p-chlorobenzoyl) peroxide [p,p -dichlorobenzoyl peroxide di-(4-chlorobenzoyl)per-oxide] [94-17-7]... [Pg.735]

In connection with Table VII it should be noted that at 80°C, 48 hr represents approximately 12 half-life periods for dibenzoyl peroxide and 45 hr is approximately 9 half-life periods for di(p-chlorobenzoyl)peroxide. This means that in... [Pg.296]

Polymerization conditions Polymerization using dibenzoyl peroxide (concentration given in first column) was conducted at 80.0° 0.3°C in sealed tubes degassed by Procedme 2 of Table VI. Di(p-chlorobenzoyl)peroxide instead of dibenzoyl peroxide. [Pg.297]

That the formation of the arylcyclohexadienyl radical in the first step is not freely reversible can be demonstrated by experiments with p-chlorobenzoyl peroxide and benzene-hexadeuteriobenzene mixtures. Although the isotope effect calculated from the deuterium content in the products is = L3, the benzene-hexadeuteriobenzene mixture... [Pg.193]

Figure 7.2 Relationship between initiator concentration and polymerization rate for different initiators A, bis(p-chlorobenzoyl)peroxide B, benzoyl peroxide C, acetyl peroxide in dimethylphthalate D, lauroyl peroxide E, myristoyl peroxide F, caprylyl peroxide G, bis(2,4 dichlorobenzoyl) peroxide. [A.I. Lowell and J.R. Price, J. Poly. Sci, 43, 1 (1996). With permission.]... [Pg.198]


See other pages where P-Chlorobenzoyl Peroxide is mentioned: [Pg.237]    [Pg.114]    [Pg.26]    [Pg.34]    [Pg.34]    [Pg.40]    [Pg.40]    [Pg.40]    [Pg.339]    [Pg.36]    [Pg.237]    [Pg.177]    [Pg.177]    [Pg.1540]    [Pg.1574]    [Pg.211]    [Pg.211]    [Pg.278]    [Pg.36]    [Pg.214]    [Pg.238]    [Pg.288]    [Pg.288]    [Pg.114]    [Pg.954]    [Pg.1020]    [Pg.284]   
See also in sourсe #XX -- [ Pg.114 ]

See also in sourсe #XX -- [ Pg.114 ]




SEARCH



3- Chlorobenzoyl peroxide

Chlorobenzoyl

© 2024 chempedia.info