Oxidising reagent

Figure 10 Sulfur-donor molecules whose C.-T. adducts with I2 or IBr have been used as oxidising reagents towards metal powders...

The earliest catalytic application of C-H bond activation and functionalisation is that of methane using platinum chlorides as the catalyst and oxidising reagent. The exchange of hydrogen atoms in arenes with D20 was... 

Redox titration using potassium permanganate as the oxidising reagent and self-indicator. 

Organolithium reagents reaction with imidothioesters 114 reaction with isothiocyanates 42 reaction with non enethiolizable dithioesters 98 Orthotrithioesters 79 cleavage of 79 reaction with ketones 137 Oxathiane Eliel reagent 19 Oxaziridines as oxidising reagents 27 Oxiranes... 

Oxidation and reduction. These reactions are mechanistically complementary to each other oxidising reagents (e.g. Section 5.7.1, p. 587) are electrophilic and reducing reagents (e.g. Section 5.4.1, p. 519) are nucleophilic. 

The oxidation step is usually carried out in situ and is illustrated by the conversion of hex-l-ene into hexan-l-ol (Expt 5.44) trimethylamine ZV-oxide has been suggested as a safer alternative oxidising reagent.65 The g.l.c. analysis of the... 

Benzyl ethers are readily formed under PTC conditions described in Expt 5.73. These ethers are stable to acidic and basic media, and to oxidising reagents. Deprotection is effected by hydrogenolysis the wide range of conditions appropriate to the structural nature of the alcohol has been reviewed.77... 

Fenton s reagent A mixture of H202 and FeS04. Used as an oxidising reagent, e g. to hydroxylate... 

Reducing sugars Sugarcane juices Microwave-assisted sugar oxidation by hexacyanoferrate(III) in alkaline medium UV-Vis 15.0 pmol I, 1 Flow injection system derivatisation using the oxidising reagent de-bubbler before measurement [443]... 

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