Oxides CO oxidation

Substrate Compounds Aerobic Anaerobic Fermentation Oxidation Co-oxidation... 

R G. Harrison, I. K. Ball, W. Azelee, W. Daniell, and D. Goldfarb, Nature and surface redox properties of copper(ll)-promoted cerium(lV) oxide CO oxidation catalysts, Chem. Mater. 12, 3715-3725 (2000). 

Phase I reactions include microsomal monooxygenations, cytosolic and mitochondrial oxidations, co-oxidations in the prostaglandin synthetase reaction, reductions, hydrolyses, and epoxide hydration. All of these reactions, with the exception of reductions, introduce polar groups to the molecule that, in most cases, can be conjugated during phase II metabolism. The major phase I reactions are summarized in Table 7.1. 

Martorana et al. (2004) Pt / ceria / zirconia Kinetics of hysteresis of metal/ nonmetal mediated reduction of storage oxide + + + CO oxidation storage mode of TWC... 

Between 2000 and 2005, several major reviews on asymmetric organic synthesis were published [10-14] which also covered some advances in the dynamic field of polymer-immobilized manganese-saien complexes. In 2000, immobilization of Jacobsen s epoxidation catalyst [26] on polystyrene and polymethacrylate resins was reported [27]. Catalytic performances were evaluated using 1,2-dihydronaphtha-lene, indene, l-phenyl-3,4-dihydronaphthalene and 1-phenylcyclohexene as substrates, and wx-chloroperbenzoic add (m-CPBA) and N-methylmorpholine-N-oxide (NMO) as oxidant/co-oxidant. Epoxide yields up to 61% and ee values up to 91%... 

Solid catalyzed reactions N20 decomposition H2 oxidation CO oxidation Hugo (1968) Beusch et al. (1970) Hugo (1970) Beusch et al. (1970) Sheintueh (1977) LC M LC s... 

Much of the current work on the mechanisms responsible for the unique Au activity have focused on understanding CO oxidation. CO oxidation is generally agreed to proceed by the adsorption of both CO and oxygen, the activation of oxygen, and the subsequent formation and desorption of It is stiU debated as to whether atomic or... 

Gustafson J, Westerstrom R, Balmes O, Resta A, van Rijn R, TorreUes X, Herbschleb CT, Erenken JWM, Lundgren E (2010) Catalytic activity of the Rh surface oxide CO oxidation over Rh(lll) under realistic conditions. J Phys Chem C 114 4580-4583... 

O-Arylation and O-Vinylations. When aryl or vinyl boronic " acids are treated with Cu(OAc)2 in the presence of base and a phenol, 0-arylation occurs giving aromatic aryl or vinyl ethers in good to excellent yields under very mild conditions (eq 24). As in the A-arylation case, both catalytic and stoichiometric versions were developed. Air, TEMPO, or pyridine A-oxide were used as the oxidants/co-oxidants in the catalytic version of the reaction. ... 

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