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Osmium complexes thiolates

Osmium tetroxide forms several thiolate complexes from interaction with thiols and triphenyl- or trialkylphosphines ... [Pg.673]

Triply bridging thiolate complexes of osmium carbonyl clusters are less common than for iron. The [Os3(CO)9(//-H)(/i3-SR)] complexes (R = Me, Et) are unstable but can be conveniently trapped as ethylene adducts subsequent regeneration of the parent complexes is facile. The X-ray structure of one such 7r-coordinated ethylene adduct, [Os3(CO)9(//-C2H4)(/r-H)(//3-SMe)], has been reported. " Very few examples of Ru clusters with 3-SR coordination (R = Bu, Pr ) have been reported in the literature. ... [Pg.751]

See other pages where Osmium complexes thiolates is mentioned: [Pg.499]    [Pg.756]    [Pg.691]    [Pg.68]    [Pg.185]    [Pg.185]    [Pg.83]    [Pg.833]    [Pg.834]    [Pg.46]    [Pg.71]    [Pg.97]    [Pg.151]    [Pg.42]    [Pg.68]    [Pg.434]    [Pg.559]    [Pg.68]    [Pg.263]    [Pg.751]    [Pg.1298]    [Pg.1299]    [Pg.4752]    [Pg.59]    [Pg.68]    [Pg.168]    [Pg.155]    [Pg.68]    [Pg.745]    [Pg.746]    [Pg.184]    [Pg.295]   
See also in sourсe #XX -- [ Pg.607 ]



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