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Osmium complexes octaethylporphyrin

The olive-green osmium(VI) octaethylporphyrin complex 0s02(0EP) (IR v(0s—0) 825 cm-1) is representative of a number of osmyP porphyrins [185] they can readily be transformed into a number of osmium porphyrins in lower oxidation states (Figure 1.73). [Pg.71]

Octaethylporphyrin (OEP) affords three osmium nitrosyl complexes Os(NO)(OMe)(OEP), made from Os(CO)py(OEP), methanol and NO 232 with HF this yields Os(NO)F(OEP)232 and with HC104 it gives 0s(N0)(0C103)(0EP).2SS The nitrosyl carbonyl complex [Os(NO)(CO)Cl2(PPh3)2]BF4 is made by reaction of Os(NO)(CO)Cl(PPh3)2 with HBF4.223... [Pg.548]

See other pages where Osmium complexes octaethylporphyrin is mentioned: [Pg.620]    [Pg.185]    [Pg.253]    [Pg.198]    [Pg.15]    [Pg.575]    [Pg.595]    [Pg.575]    [Pg.595]    [Pg.4049]    [Pg.409]   
See also in sourсe #XX -- [ Pg.618 ]

See also in sourсe #XX -- [ Pg.4 , Pg.617 , Pg.618 ]



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