Organozinc thiolates

FIGURE 105. Solid state stmcture of the monomeric organozinc thiolate 228... 

FIGURE 106. Schematic structures of dimeric organozinc thiolates 229-232... 

Organozinc thiolates, dithiocarbaraates, and possibly other sulfur derivatives, are frequently associated through additional Zn-S bonds, although the Zn-S bond is less polar. Supramolecular aggregates of various degrees of association, including dimers, trimers, tetramers, pentamers, and octamers, have been reported. 

These 0x0 Re complexes can furnish various derivatives, for example, with N-, 0-, S-, or C- ligands, that is, Re oxo-amido, -imido, -alkoxide, -phenoxide, -diolate, -thiolate, -alkyl, or - aryl complexes, on reactions of (13) or (14) with amines, alcohols, phenoxides, diols, thiols, organozinc, or Grignard reagents, respectively. 

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