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Organosilane Reduction of Imines

Cl3SiH, MeCN, reflux, 4 h Cl3SiH (1.2 eq), C6H6, reflux, 4 h [Pg.586]

Various chiral ligands with metal catalysts can be employed in the organosilane reduction of imines to amines. Many of these provide modest success. These include (oxazolino)diphenylphosphinoferrocene ligands with ruthenium,605 (—)-DIOP/Rh(I),606,607 3,3 -BINOL (l,l -bi-2-naphthol) and LiHMDS,608 and (S)-phenyl V-formylprolinamidc with trichlorosilane.609... [Pg.110]

TABLE 34. ASYMMETRIC ORGANOSILANE REDUCTION OF IMINES (Continued)... [Pg.706]

Supplemental References for Table 23. Organosilane Reduction of Imines... [Pg.743]

The organosilane reduction of pentafluorophenyl acrylate in the presence of an imine was shown to lead to /1-lactams in good yields (Eq. 295)476 The conversion of an ethyl ynoate into an E-ethyl enoate in high yield is shown in Eq. 296 477... [Pg.95]

See other pages where Organosilane Reduction of Imines is mentioned: [Pg.582]    [Pg.584]    [Pg.586]    [Pg.588]    [Pg.590]    [Pg.592]    [Pg.705]    [Pg.582]    [Pg.584]    [Pg.586]    [Pg.588]    [Pg.590]    [Pg.592]    [Pg.705]    [Pg.101]    [Pg.110]    [Pg.983]    [Pg.304]   


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Asymmetric Organosilane Reduction of Imines

Imines reduction

Of imines

Organosilane Reductions

Organosilanes

Reduction of imines

Reductive imine

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