Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Organosilane Reduction of Amides

Supplemental References for Table 13. Organosilane Reduction of Amides... [Pg.741]

TABLE 18. ORGANOSILANE REDUCTION OF a,p-UNSATURATED AMIDES (Continued)... [Pg.532]

Supplemental Reference for Table 18. Organosilane Reduction of ce,p-Unsaturated Amides... [Pg.742]

Reductive Amidation of Aldehydes. The reductive amidation of aldehydes using an organosilane as the reducing agent has been realized. Benzaldehyde reacts over a 74-hour period with triethylsilane and acetonitrile in 75% aqueous sulfuric acid at room temperature to produce an 80% isolated yield of N-benzylacetamide (Eq. 169).313 Octanal fails to react under the same conditions.313 Reductive amidation of aldehydes also occurs with the reagent combination Et3SiH/TFA/primary amide (Eq. 170).326... [Pg.63]

See other pages where Organosilane Reduction of Amides is mentioned: [Pg.446]    [Pg.448]    [Pg.450]    [Pg.452]    [Pg.454]    [Pg.446]    [Pg.448]    [Pg.450]    [Pg.452]    [Pg.454]    [Pg.87]    [Pg.531]    [Pg.983]    [Pg.367]    [Pg.101]    [Pg.656]    [Pg.702]   


SEARCH



Amidation reductive

Amides reduction

Organosilane Reductions

Organosilanes

Reduction of amides

© 2024 chempedia.info