Organophosphorus derivatives

Organophosphorus Derivatives. Neopentyl glycol treated with pyridine and phosphorus trichloride in anhydrous dioxane yields the cycHc hydrogen phosphite, 5,5-dimethyl-l,3-dioxaphosphorinane 2-oxide (2) (32,33). Compounds of this type maybe useful as flameproofing plasticizers, stabilizers, synthetic lubricants, oil additives, pesticides, or intermediates for the preparation of other organophosphoms compounds (see Flame retardants Phosphorus compounds). 

The recommended names for these compounds (phosphinic acid and phosphinates) have not yet gained wide acceptance for inorganic compounds but are generally used for organophosphorus derivatives. Hypophosphites can be made by healing white phosphorus in aqueous alkali ... 

The Rise of Organophosphorus Derivatives in n-Conjugated Materials Chemistry... 

Hirsch A, Vostrowsky O (2001) Dendrimers with Carbon Rich-Cores. 217 51-93 Hirsch A, Vostrowsky O (2005) Functionalization of Carbon Nanotubes. 245 193-237 Hissler M, Dyer PW, Reau R (2005) The Rise of Organophosphorus Derivatives in p-Conjugated Materials Chemistry. 250 127-163 Hiyama T, Shirakawa E (2002) Organosilicon Compounds. 219 61-85 Holmberg K, see Hager M (2003) 227 53-74... 

Vioux A, Le Bideau J, Mutin PH, Leclercq D (2003) Hybrid Organic-Inorganic Materials Based on Organophosphorus Derivatives. 232 145-174 Vliegenthart JFG, see Haseley SR (2002) 218 93-114... 

Microwaves were used to support S-arylation of 5-substituted oxadiazoline-2-thiones <2000BMC69> and <2000M1207>. 5-(4-Pyridyl)oxadiazoline-2-thiones treated with 2-haloesters also afforded A-alkyl derivatives <2000CHE851>. A similar reaction occurred in the case of 5-pyrazolyloxadiazoline-2-thiones <2000JFA5312>. Organophosphorus derivatives of 1,3,4-oxadiazole were obtained by the reaction of bis(oxadiazolinethiones) with 0,0-diethylchlorophosphate (Scheme 21) <1998JFA1609>. 

Organophosphorus derivatives, with P-C bonds, 19 23-24t Organophosphorus extractants,... 

P-C bonds, organophosphorus derivatives with, 19 23-24t. See also Phosphorus-carbon bond... 

Hybrid Organic-Inorganic Materials Based on Organophosphorus Derivatives... 

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