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Organometallics oxidative coupling with

A molybdenum-mediated oxidative coupling of aniline 1 with cyclohexene 2a provides carbazole 3. Alternatively, the same overall transformation of aniline 1 to carbazole 3 is achieved by iron-mediated oxidative coupling with cyclo-hexa-1,3-diene 2b or by palladium-catalyzed oxidative coupling with arenes 2c. The use of appropriately substituted anilines and unsaturated six-membered hydrocarbons opens up the way to highly convergent organometallic syntheses of carbazole alkaloids. [Pg.122]

Oxidative coupling of organometallic precursors with alkenes, alkynes, conjugated and nonconjugated polyenes and polyalkynes remains the main method of synthesizing various classes of five-membered rings with other elements. However, some alternative methods do exist. [Pg.1287]

See other pages where Organometallics oxidative coupling with is mentioned: [Pg.21]    [Pg.52]    [Pg.759]    [Pg.407]    [Pg.154]    [Pg.155]    [Pg.739]    [Pg.55]    [Pg.33]    [Pg.121]    [Pg.163]    [Pg.224]    [Pg.227]    [Pg.286]    [Pg.36]    [Pg.537]    [Pg.361]    [Pg.154]    [Pg.155]    [Pg.33]    [Pg.71]    [Pg.55]    [Pg.154]    [Pg.332]    [Pg.56]    [Pg.536]    [Pg.296]    [Pg.202]    [Pg.203]    [Pg.340]    [Pg.54]    [Pg.122]    [Pg.52]    [Pg.51]    [Pg.255]    [Pg.24]    [Pg.1086]    [Pg.4106]    [Pg.4844]    [Pg.473]    [Pg.61]    [Pg.14]    [Pg.361]    [Pg.1365]    [Pg.5]   
See also in sourсe #XX -- [ Pg.100 ]



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Organometallic oxidant

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