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Organoaluminum species

The structures of substantial numbers of simple organoaluminum species have been reported during the past few years. The initial structure determined was that of trimethylaluminum (IV) (68). Subsequently, the structure has been redetermined in the solid state (116) and attempts have even been made to determine the location of the hydrogen atoms to provide details concerning the bonding present within this molecule (54). [Pg.239]

Although the ultimate fate of the nitrosyl ligands has not been established, a reasonable pathway for their removal can be postulated based on our IR data and recent literature results. Shriver et al. (42) have found that organoaluminum species will complex with the oxygen of metal-coordinated carbonyl groups. For example, the six-coordinate... [Pg.212]

The mechanism of addition of aikylmagnesium halides to double bonds has been the subject of intensive investigation.6 According to the current interpretation, these reactions differ significantly in mechanism from reactions with organoaluminum species under similar reaction conditions. For this reason no general mechanism for can be lormulated carbometallation reactions. [Pg.254]

Organoaluminum compounds have been used for the preparation of mono and bimetallic nanoparticles by a reductive stabilization method (Equation (6.2). The results are summarized in Table 6.2. 2i The study shows that metal nanoparticles are stabilized by a layer of organoaluminum species. [Pg.100]

Simple Trivalent Organoaluminum Species Perspectives on Structure, Bonding. [Pg.3]

The present contribution is structured around three main classes of organoaluminum species. [Pg.3]

Fig. 11 Structural diversity in organoaluminum species supported by Schiff bases... Fig. 11 Structural diversity in organoaluminum species supported by Schiff bases...
Fig. 25 Organoaluminum species bearing a thioacetamido pyrazolyl ligand... Fig. 25 Organoaluminum species bearing a thioacetamido pyrazolyl ligand...
Fig. 28 A iV,iV -chelated organoaluminum species with a phosphine-phosphonium/phosphine-stabilized phosphonium moiety... Fig. 28 A iV,iV -chelated organoaluminum species with a phosphine-phosphonium/phosphine-stabilized phosphonium moiety...
Use of Organoaluminum Species Supported by Chelating Ligands Selected Examples... [Pg.34]

Organoaluminum Species Bearing N- andlor 0-Type Ligands... [Pg.34]

See other pages where Organoaluminum species is mentioned: [Pg.1510]    [Pg.118]    [Pg.213]    [Pg.17]    [Pg.140]    [Pg.246]    [Pg.284]    [Pg.354]    [Pg.355]    [Pg.358]    [Pg.361]    [Pg.1165]    [Pg.47]    [Pg.381]    [Pg.341]    [Pg.226]    [Pg.159]    [Pg.159]    [Pg.185]    [Pg.24]    [Pg.32]   
See also in sourсe #XX -- [ Pg.54 , Pg.56 , Pg.65 , Pg.350 , Pg.420 ]

See also in sourсe #XX -- [ Pg.70 ]



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