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Organic polymers with silicate films

Fig. 21 (continued) (d) Arrhenius plot of the relaxation times obtained by dielectric spectroscopy for bulk poly(methylphenylsiloxane) (PMPS) (1) and PMPS intercalated into organically modified layered silicates (1.5-2.0nm thick polymer films) (2) [41]. (e) DSC curves of neat PS (1), physical mixture of PS with the organically modified sdicate (2), and PS intercalated (nanoconfined) between sdicate nanolayers (3) [40]. (f) Unfreezing large-amplitude dynamics in bulk PS (1) and in 2 nm layer of PS confined between the organically modified surfaces of layered fluorohectorite (2) mobUe fraction vs temperature plots ( H quadrupole NMR spin-echo experiments [47])... [Pg.110]

It should be stressed that our objective is to block one Si-bond, and the small methyl group is sufficient for this purpose, yet it does not introduce an organic-polymer modification of the silicate (14), which is not necessary for our purposes. Crack-free supported thin films were attained right from the first sol-gel preparations with this... [Pg.411]

See other pages where Organic polymers with silicate films is mentioned: [Pg.1523]    [Pg.1528]    [Pg.255]    [Pg.272]    [Pg.370]    [Pg.35]    [Pg.1816]    [Pg.116]    [Pg.646]    [Pg.526]    [Pg.429]    [Pg.550]    [Pg.175]    [Pg.123]    [Pg.582]    [Pg.433]    [Pg.236]    [Pg.4]    [Pg.5]    [Pg.131]    [Pg.61]    [Pg.788]    [Pg.680]    [Pg.423]    [Pg.207]    [Pg.49]    [Pg.275]    [Pg.499]    [Pg.74]    [Pg.118]    [Pg.98]    [Pg.416]    [Pg.379]    [Pg.269]    [Pg.134]    [Pg.407]    [Pg.817]    [Pg.81]    [Pg.99]    [Pg.301]    [Pg.39]    [Pg.226]    [Pg.4047]    [Pg.5007]    [Pg.135]    [Pg.111]    [Pg.404]    [Pg.245]   
See also in sourсe #XX -- [ Pg.340 ]



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Organic films

Organic polymers

Silicate films

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