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Olefins conformational changes

Berkessel A, Adrio JA (2004) Kinetic studies of olefin epoxidation with hydrogen peroxide in l,l,l,3,3,3-hexafluoro-2-propanol reveal a crucial catalytic role for solvent clusters. Adv Synth Catal 346 275-280 Berkessel A, Adrio JA (2006) Dramatic acceleration of olefin epoxidation in fluorinated alcohols activation of hydrogen peroxide by multiple H-bond networks. J Am Chem Soc 128 13412-13420 Berkessel A, Adrio JA, Huttenhain D, Neudorfl JM (2006a) Unveiling the booster effect of fluorinated alcohol solvents aggregation-induced conformational changes, and cooperatively enhanced H-bonding. J Am Chem Soc 128 8421-8426... [Pg.295]

The opposite is tme of cyclic structures in the backbones, as was shown in poly(ethylene terephthalate). Actually, cyclic structures not only inhibit conformational changes but can also make crystallization more difficult. Among the polymers of a-olefins the structures of the pendant groups can influence the melting point [6]. All linear polyethylene melts between 132 and 136°C [7]. Isotactic polypropylene, on the other hand melts at 168°C [8]. [Pg.20]

CONFORMATIONAL CHANGES IN FIVE- OR SIX-MEMBER METALLACYCLES INVOLVING COORDINATED OLEFINS... [Pg.152]

See other pages where Olefins conformational changes is mentioned: [Pg.155]    [Pg.70]    [Pg.39]    [Pg.86]    [Pg.1056]    [Pg.306]    [Pg.179]    [Pg.118]    [Pg.49]    [Pg.47]    [Pg.42]    [Pg.104]    [Pg.174]    [Pg.375]    [Pg.351]    [Pg.119]    [Pg.232]    [Pg.154]    [Pg.112]    [Pg.533]    [Pg.174]    [Pg.180]    [Pg.32]    [Pg.230]    [Pg.574]    [Pg.61]    [Pg.334]    [Pg.204]    [Pg.107]    [Pg.186]    [Pg.84]    [Pg.359]    [Pg.376]    [Pg.399]    [Pg.300]    [Pg.323]    [Pg.4]    [Pg.568]    [Pg.121]    [Pg.155]    [Pg.193]    [Pg.352]    [Pg.238]    [Pg.196]    [Pg.162]   


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Conformation change

Conformational changes

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